- -

State of the art of Lewis acid-containing zeolites: lessons from fine chemistry to new biomass transformation processes

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

State of the art of Lewis acid-containing zeolites: lessons from fine chemistry to new biomass transformation processes

Show simple item record

Files in this item

dc.contributor.author Moliner Marin, Manuel es_ES
dc.date.accessioned 2016-01-29T08:09:14Z
dc.date.available 2016-01-29T08:09:14Z
dc.date.issued 2014
dc.identifier.issn 1477-9226
dc.identifier.uri http://hdl.handle.net/10251/60345
dc.description.abstract [EN] The former synthesis of TS-1 opened new catalytic opportunities for zeolites, especially for their application as selective redox catalysts in several fine chemistry processes. Interestingly, isolated Ti species in the framework positions of hydrophobic zeolites, such as high silica zeolites, offer unique Lewis acid sites even in the presence of protic polar solvents (such as water). Following this discovery, other transition metals (such as Sn, Zr, V, Nb, among others) have been introduced in the framework positions of different hydrophobic zeolitic structures, allowing their application in new fine chemistry processes as very active and selective redox catalysts. Recently, these hydrophobic metallozeolites have been successfully applied as efficient catalysts for several biomass-transformation processes in bulk water. The acquired knowledge from the former catalytic descriptions in fine chemistry processes using hydrophobic Lewis acid-containing zeolites has been essential for their application in these novel biomass transformations. In the present review, I will describe the recent advances in the synthesis of new transition metal-containing zeolites presenting Lewis acid character, and their unique catalytic applications in both fine chemistry and novel biomass-transformations. es_ES
dc.description.sponsorship This work has been supported by the Spanish Government-MINECO (MAT2012-37160), Consolider Ingenio 2010-Multicat, and UPV through PAID-06-11 (no. 1952). Manuel Moliner also acknowledges the "Subprograma Ramon y Cajal" for the contract RYC-2011-08972. ITQ thanks the "Program Severo Ochoa" for financial support.
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation MINECO/MAT2012-37160 es_ES
dc.relation UPV/PAID-06-11/1952 es_ES
dc.relation MICINN/RYC-2011-08972 es_ES
dc.relation.ispartof Dalton Transactions es_ES
dc.rights Reserva de todos los derechos es_ES
dc.title State of the art of Lewis acid-containing zeolites: lessons from fine chemistry to new biomass transformation processes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/C3DT52293H
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Moliner Marin, M. (2014). State of the art of Lewis acid-containing zeolites: lessons from fine chemistry to new biomass transformation processes. Dalton Transactions. 43:4197-4208. doi:10.1039/C3DT52293H es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c3dt52293h es_ES
dc.description.upvformatpinicio 4197 es_ES
dc.description.upvformatpfin 4208 es_ES
dc.type.version info:eu repo/semantics/publishedVersion es_ES
dc.description.volume 43 es_ES
dc.relation.senia 286933 es_ES
dc.identifier.pmid 24142026
dc.contributor.funder Ministerio de Economía y Competitividad (MINECO)
dc.contributor.funder Universitat Politècnica de València (UPV)
dc.contributor.funder Ministerio de Ciencia e Innovación (MICINN)


This item appears in the following Collection(s)

Show simple item record