Mostrar el registro sencillo del ítem
dc.contributor.author | Súbová, I. | es_ES |
dc.contributor.author | Assandas, A. K. | es_ES |
dc.contributor.author | Catalá-Icardo, Mónica | es_ES |
dc.contributor.author | Martínez Calatayud, J. | es_ES |
dc.date.accessioned | 2016-02-02T15:41:27Z | |
dc.date.available | 2016-02-02T15:41:27Z | |
dc.date.issued | 2006-01 | |
dc.identifier.issn | 0910-6340 | |
dc.identifier.uri | http://hdl.handle.net/10251/60489 | |
dc.description.abstract | [EN] This paper presents the analytical determination of the pesticide Asulam based on its native fluorescence. The method was optimized in either a flow injection analysis (FIA) assembly or in batch. The maximum fluorescence intensity was observed for basic pH solutions and at a lambda(ex) of 258 nm and lambda(em) of 342 nm. The influence of different empirical parameters, such as the pH, the presence of surfactants, solvent polarity or solved oxygen amount, was studied. The calibration range was fitted with a linear equation from 0.01-3 mg l(-1) Asulam and 0.005-15 mg l(-1) Asulam for batch and continuous-flow, respectively. The RSD for both procedures was 1.0%. After testing the influence of a large series of potential interferents, the method was applied to water samples from different locations. | es_ES |
dc.description.sponsorship | This research was supported Ministerio Educación y Ciencia (Spanish Government), Project BQU2002-04248-C02-01 | |
dc.language | Inglés | es_ES |
dc.relation.ispartof | Analytical Sciences | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Carbamates | es_ES |
dc.subject | Flow injection analysis | es_ES |
dc.subject | Fresh water | es_ES |
dc.subject | Herbicides | es_ES |
dc.subject | Hydrogen-Ion concentration | es_ES |
dc.subject | Molecular structure | es_ES |
dc.subject | Pesticide residues | es_ES |
dc.subject | Sensitivity and specificity | es_ES |
dc.subject | Spectrometry | es_ES |
dc.subject | Fluorescence | es_ES |
dc.subject.classification | QUIMICA ANALITICA | es_ES |
dc.title | Fluorescence determination of the pesticide Asulam by flow injection analysis | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.2116/analsci.22.21 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICYT//BQU2002-04248-C02-01/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto de Investigación para la Gestión Integral de Zonas Costeras - Institut d'Investigació per a la Gestió Integral de Zones Costaneres | es_ES |
dc.description.bibliographicCitation | Súbová, I.; Assandas, AK.; Catalá-Icardo, M.; Martínez Calatayud, J. (2006). Fluorescence determination of the pesticide Asulam by flow injection analysis. Analytical Sciences. 22(1):21-24. https://doi.org/10.2116/analsci.22.21 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.2116/analsci.22.21 | es_ES |
dc.description.upvformatpinicio | 21 | es_ES |
dc.description.upvformatpfin | 24 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 22 | es_ES |
dc.description.issue | 1 | es_ES |
dc.relation.senia | 27488 | es_ES |
dc.identifier.eissn | 1348-2246 | |
dc.identifier.pmid | 16429766 | |
dc.contributor.funder | Ministerio de Ciencia y Tecnología |