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Enantioselective Friedel-Crafts Alkylation of Indoles with (E)-1-Aryl-4-benzyloxybut-2-en-1-ones Catalyzed by an (R)-3,3-Br2BINOLate-Hafnium(IV) Complex

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Enantioselective Friedel-Crafts Alkylation of Indoles with (E)-1-Aryl-4-benzyloxybut-2-en-1-ones Catalyzed by an (R)-3,3-Br2BINOLate-Hafnium(IV) Complex

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Muñoz Roca, MDC. (2013). Enantioselective Friedel-Crafts Alkylation of Indoles with (E)-1-Aryl-4-benzyloxybut-2-en-1-ones Catalyzed by an (R)-3,3-Br2BINOLate-Hafnium(IV) Complex. European Journal of Organic Chemistry. 1902-1907. https://doi.org/10.1002/ejoc.201201636

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Título: Enantioselective Friedel-Crafts Alkylation of Indoles with (E)-1-Aryl-4-benzyloxybut-2-en-1-ones Catalyzed by an (R)-3,3-Br2BINOLate-Hafnium(IV) Complex
Autor: Muñoz Roca, María del Carmen
Entidad UPV: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Fecha difusión:
Resumen:
A highly enantioselective Friedel–Crafts reaction of unprotected indoles with (E)-1-aryl-4-benzyloxybut-2-en-1-ones catalyzed by a new chiral [Hf{(R)-3,3′-Br2-BINOL}(OtBu)2]2 complex has been developed to functionalize the ...[+]
Palabras clave: Alkylation , Asymmetric catalysis , C–C coupling , Hafnium , Regioselectivity
Derechos de uso: Cerrado
Fuente:
European Journal of Organic Chemistry. (issn: 1434-193X ) (eissn: 1099-0690 )
DOI: 10.1002/ejoc.201201636
Editorial:
Wiley-VCH Verlag
Versión del editor: http://dx.doi.org/10.1002/ejoc.201201636.
Código del Proyecto:
info:eu-repo/grantAgreement/MICINN//CTQ2009-13083/ES/Desarrollo de nuevos procesos enantioselectivos de formación de enlaces C-C mediante catálisis asimétrica/
info:eu-repo/grantAgreement/GVA//ISIC%2F2012%2F001/
info:eu-repo/grantAgreement/GVA//ACOMP%2F2012%2F212/
Agradecimientos:
Financial support from the Ministerio de Ciencia e Innovacion, Gobierno de Espana and FEDER, European Union (Grant CTQ 2009-13083) and the Generalitat Valenciana (Grants ACOMP/2012/212 and ISIC 2012/001) is acknowledged. ...[+]
Tipo: Artículo

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