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Making C-C bonds with gold: identification of selective gold sites for homo- and cross-coupling reactions between iodobenzene and alkynes

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Making C-C bonds with gold: identification of selective gold sites for homo- and cross-coupling reactions between iodobenzene and alkynes

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Boronat Zaragoza, M.; Combita Merchán, DF.; Concepción Heydorn, P.; Corma Canós, A.; García Gómez, H.; Juárez Marín, R.; Laursen ., SO.... (2012). Making C-C bonds with gold: identification of selective gold sites for homo- and cross-coupling reactions between iodobenzene and alkynes. Journal of Physical Chemistry C. 116(47):24855-24867. doi:10.1021/jp3071585

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/61499

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Title: Making C-C bonds with gold: identification of selective gold sites for homo- and cross-coupling reactions between iodobenzene and alkynes
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
The nature of the active sites involved in the gold catalyzed Sonogashira cross-coupling reaction between iodobenzene and phenylacetylene, and in the competitive homocoupling reactions, has been investigated by means of ...[+]
Subjects: FINDING SADDLE-POINTS , SONOGASHIRA REACTION , ENERGY , PHENYLACETYLENE , NANOPARTICLES , ELIMINATION , ALGORITHM , OXIDATION , CATALYSTS , SURFACES
Copyrigths: Cerrado
Source:
Journal of Physical Chemistry C. (issn: 1932-7447 )
DOI: 10.1021/jp3071585
Publisher:
American Chemical Society
Publisher version: http://dx.doi.org/10.1021/jp3071585
Thanks:
Financial support by the Spanish MICINN (CONSOLIDER Ingenio 2010-MULTICAT) and Generalitat Valenciana (PROMETEO project 2088/130) is gratefully acknowledged. R.J. and D.C. thank the Spanish MICINN for postgraduate scolarships, ...[+]
Type: Artículo

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