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Superior performance of metal-organic frameworks over zeolites as solid acid catalysts in the prins reaction: Green synthesis of nopol

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Superior performance of metal-organic frameworks over zeolites as solid acid catalysts in the prins reaction: Green synthesis of nopol

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dc.contributor.author Opanasenko, Maksym es_ES
dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Hwang, Young Kyu es_ES
dc.contributor.author Chang, Jong-San es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Cejka, Jiri es_ES
dc.date.accessioned 2016-03-07T13:32:29Z
dc.date.issued 2013-05
dc.identifier.issn 1864-5631
dc.identifier.uri http://hdl.handle.net/10251/61530
dc.description.abstract [EN] The catalytic performance of a set of metal-organic frameworks [CuBTC, FeBTC, MIL-100(Fe), MIL-100(Cr), ZIF-8, MIL-53(Al)] was investigated in the Prins condensation of b-pinene with formaldehyde and compared with the catalytic behavior of conventional aluminosilicate zeolites BEA and FAU and titanosilicate zeolite MFI (TS-1). The activity of the investigated metal-organic frameworks (MOFs) increased with the increasing concentration of accessible Lewis acid sites in the order ZIF-8 <MIL-53(Al) <FeBTC <MIL-100(Cr) <MIL-100(Fe). Unwanted b-pinene-like isomerization takes place on the strong Br?sted acid sites of zeolites BEA and FAU, which showed significantly lower selectivity to the target nopol than the MOFs. Its high activity, the preservation of its structure and active sites, and the possibility to use it in at least three catalytic cycles without loss of activity make MIL-100 (Fe) the best performing catalyst of the series for the Prins condensation of b-pinene and paraformaldehyde. Our report exemplifies the advantages of MOFs over zeolites as solid catalysts in liquidphase reactions for the production of fine chemicals. es_ES
dc.description.sponsorship The research of MO that led to these results was funded by the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement no. 228862. JC. thanks the Czech Grant Agency for financial support (Centre of Excellence-P106/12/G015). JSC and YKH are grateful to KRICT and NRF/KICOS for financial support for the Institutional Research Grant (KK-1201-F0) and the International Collaboration Programme (KN-1127). en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof ChemSusChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject C-C coupling es_ES
dc.subject Green chemistry es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Zeolites es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Superior performance of metal-organic frameworks over zeolites as solid acid catalysts in the prins reaction: Green synthesis of nopol es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cssc.201300032
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/
dc.relation.projectID info:eu-repo/grantAgreement/GACR//P106%2F12%2FG015/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/KRICT//KK-1201-F/
dc.relation.projectID info:eu-repo/grantAgreement/KICOS//KN-1127/
dc.relation.projectID info:eu-repo/grantAgreement/KICOS//KK-1201-F0/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Opanasenko, M.; Dhakshinamoorthy, A.; Hwang, YK.; Chang, J.; García Gómez, H.; Cejka, J. (2013). Superior performance of metal-organic frameworks over zeolites as solid acid catalysts in the prins reaction: Green synthesis of nopol. ChemSusChem. 6(5):865-871. https://doi.org/10.1002/cssc.201300032 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cssc.201300032 es_ES
dc.description.upvformatpinicio 865 es_ES
dc.description.upvformatpfin 871 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 6 es_ES
dc.description.issue 5 es_ES
dc.relation.senia 262465 es_ES
dc.identifier.eissn 1864-564X
dc.contributor.funder Czech Science Foundation
dc.contributor.funder Korea Research Institute of Chemical Technology
dc.contributor.funder National Research Foundation of Korea
dc.contributor.funder European Commission
dc.contributor.funder Korea Foundation for International Cooperation of Science and Technology


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