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dc.contributor.author | Opanasenko, Maksym | es_ES |
dc.contributor.author | Dhakshinamoorthy, Amarajothi | es_ES |
dc.contributor.author | Hwang, Young Kyu | es_ES |
dc.contributor.author | Chang, Jong-San | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.contributor.author | Cejka, Jiri | es_ES |
dc.date.accessioned | 2016-03-07T13:32:29Z | |
dc.date.issued | 2013-05 | |
dc.identifier.issn | 1864-5631 | |
dc.identifier.uri | http://hdl.handle.net/10251/61530 | |
dc.description.abstract | [EN] The catalytic performance of a set of metal-organic frameworks [CuBTC, FeBTC, MIL-100(Fe), MIL-100(Cr), ZIF-8, MIL-53(Al)] was investigated in the Prins condensation of b-pinene with formaldehyde and compared with the catalytic behavior of conventional aluminosilicate zeolites BEA and FAU and titanosilicate zeolite MFI (TS-1). The activity of the investigated metal-organic frameworks (MOFs) increased with the increasing concentration of accessible Lewis acid sites in the order ZIF-8 <MIL-53(Al) <FeBTC <MIL-100(Cr) <MIL-100(Fe). Unwanted b-pinene-like isomerization takes place on the strong Br?sted acid sites of zeolites BEA and FAU, which showed significantly lower selectivity to the target nopol than the MOFs. Its high activity, the preservation of its structure and active sites, and the possibility to use it in at least three catalytic cycles without loss of activity make MIL-100 (Fe) the best performing catalyst of the series for the Prins condensation of b-pinene and paraformaldehyde. Our report exemplifies the advantages of MOFs over zeolites as solid catalysts in liquidphase reactions for the production of fine chemicals. | es_ES |
dc.description.sponsorship | The research of MO that led to these results was funded by the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement no. 228862. JC. thanks the Czech Grant Agency for financial support (Centre of Excellence-P106/12/G015). JSC and YKH are grateful to KRICT and NRF/KICOS for financial support for the Institutional Research Grant (KK-1201-F0) and the International Collaboration Programme (KN-1127). | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-VCH Verlag | es_ES |
dc.relation.ispartof | ChemSusChem | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | C-C coupling | es_ES |
dc.subject | Green chemistry | es_ES |
dc.subject | Heterogeneous catalysis | es_ES |
dc.subject | Metal-organic frameworks | es_ES |
dc.subject | Zeolites | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Superior performance of metal-organic frameworks over zeolites as solid acid catalysts in the prins reaction: Green synthesis of nopol | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1002/cssc.201300032 | |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/GACR//P106%2F12%2FG015/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/KRICT//KK-1201-F/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/KICOS//KN-1127/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/KICOS//KK-1201-F0/ | |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Opanasenko, M.; Dhakshinamoorthy, A.; Hwang, YK.; Chang, J.; García Gómez, H.; Cejka, J. (2013). Superior performance of metal-organic frameworks over zeolites as solid acid catalysts in the prins reaction: Green synthesis of nopol. ChemSusChem. 6(5):865-871. https://doi.org/10.1002/cssc.201300032 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/cssc.201300032 | es_ES |
dc.description.upvformatpinicio | 865 | es_ES |
dc.description.upvformatpfin | 871 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 6 | es_ES |
dc.description.issue | 5 | es_ES |
dc.relation.senia | 262465 | es_ES |
dc.identifier.eissn | 1864-564X | |
dc.contributor.funder | Czech Science Foundation | |
dc.contributor.funder | Korea Research Institute of Chemical Technology | |
dc.contributor.funder | National Research Foundation of Korea | |
dc.contributor.funder | European Commission | |
dc.contributor.funder | Korea Foundation for International Cooperation of Science and Technology |