Mostrar el registro sencillo del ítem
dc.contributor.author | Serna Merino, Pedro Manuel | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2016-03-07T13:43:07Z | |
dc.date.issued | 2014-08 | |
dc.identifier.issn | 1864-5631 | |
dc.identifier.uri | http://hdl.handle.net/10251/61533 | |
dc.description.abstract | [EN] We show that gold nanoparticles are able to perform the direct oxidative coupling of nonactivated aromatics with O-2 as the only co-reagent. In this reaction, the aromatic acts both as reactant and solvent. Biphenyl, for example, can be obtained from benzene with high selectivity and a turnover number (TON) of 230 per pass. Similarly, several substituted biaryls can be prepared. Pd performs only one TON and even when a second catalytic functionality is introduced, together with strong acidic conditions, TON is always lower than 100. Other catalysts require iodine for performing the reaction, leading to 2 kg of waste for 1 kg of biphenyl formed, whereas no waste is created by the oxidative coupling with gold nanoparticles. | es_ES |
dc.description.sponsorship | The research was supported by Project CONSOLIDER INGENIO (MULTICAT), The SEVERO OCHOA Program for centres of excellence, the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement PIOF-GA-2009-253129 (P.S.) | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-VCH Verlag | es_ES |
dc.relation.ispartof | ChemSusChem | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | arenes | es_ES |
dc.subject | c-c coupling | es_ES |
dc.subject | gold | es_ES |
dc.subject | nanoparticles | es_ES |
dc.subject | supported catalysts | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Towards a zero-waste oxidative coupling of nonactivated aromatics by supported gold nanoparticles | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1002/cssc.201402061 | |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/253129/EU/Study of uniform supported metal complexes and metal clusters at atomic level for catalytic applications/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Serna Merino, PM.; Corma Canós, A. (2014). Towards a zero-waste oxidative coupling of nonactivated aromatics by supported gold nanoparticles. ChemSusChem. 7(8):2136-2139. https://doi.org/10.1002/cssc.201402061 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/cssc.201402061 | es_ES |
dc.description.upvformatpinicio | 2136 | es_ES |
dc.description.upvformatpfin | 2139 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 7 | es_ES |
dc.description.issue | 8 | es_ES |
dc.relation.senia | 281805 | es_ES |
dc.identifier.eissn | 1864-564X | |
dc.identifier.pmid | 24889545 | |
dc.contributor.funder | European Commission | |
dc.contributor.funder | Ministerio de Economía y Competitividad |