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Cascade reactions catalyzed by metal organic frameworks

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Cascade reactions catalyzed by metal organic frameworks

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2016-03-07T13:48:54Z
dc.date.issued 2014-09
dc.identifier.issn 1864-5631
dc.identifier.uri http://hdl.handle.net/10251/61534
dc.description.abstract [EN] Cascade or tandem reactions where two or more individual reactions are carried out in one pot constitute a clear example of process intensification, targeting the maximization of spatial and temporal productivity with mobilization of minimum resources. In the case of catalytic reactions, cascade processes require bi-/multifunctional catalysts that contain different classes of active sites. Herein, we show that the features and properties of metal-organic frameworks (MOFs) make these solids very appropriate materials for the development of catalysts for cascade reactions. Due to composition and structure, MOFs can incorporate different types of sites at the metal nodes, organic linkers, or at the empty internal pores, allowing the flexible design and synthesis of multifunctional catalysts. After some introductory sections on the relevance of cascade reactions from the point of view of competitiveness, sustainability, and environmental friendliness, the main part of the text provides a comprehensive review of the literature reporting the use of MOFs as heterogeneous catalysts for cascade reactions including those that combine in different ways acid/base, oxidation/reduction, and metal-organic centers. The final section summarizes the current state of the art, indicating that the development of a first commercial synthesis of a high-added-value fine chemical will be a crucial milestone in this area. es_ES
dc.description.sponsorship A.D.M. thanks University Grants Commission, New Delhi for the award of Assistant Professorship under its Faculty Recharge Programme. Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and Generalidad Valenciana (Prometeo is gratefully acknowledged.
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation MINECO/CTQ2012-32315 es_ES
dc.relation.ispartof ChemSusChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Cascade/tandem reactions es_ES
dc.subject Coupling es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Sustainable chemistry es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Cascade reactions catalyzed by metal organic frameworks es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cssc.201402148
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; García Gómez, H. (2014). Cascade reactions catalyzed by metal organic frameworks. ChemSusChem. 7(9):2392-2410. doi:10.1002/cssc.201402148 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cssc.201402148 es_ES
dc.description.upvformatpinicio 2392 es_ES
dc.description.upvformatpfin 2410 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 7 es_ES
dc.description.issue 9 es_ES
dc.relation.senia 285716 es_ES
dc.identifier.eissn 1864-564X
dc.identifier.pmid 25082205
dc.contributor.funder Ministerio de Economía y Competitividad


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