dc.contributor.author |
El Sayed Shehata Nasr, Sameh
|
es_ES |
dc.contributor.author |
Pascual Vidal, Lluís
|
es_ES |
dc.contributor.author |
Agostini, Alessandro
|
es_ES |
dc.contributor.author |
Martínez-Máñez, Ramón
|
es_ES |
dc.contributor.author |
Sancenón Galarza, Félix
|
es_ES |
dc.contributor.author |
Costero Nieto, Ana María
|
es_ES |
dc.contributor.author |
Parra Álvarez, Margarita
|
es_ES |
dc.contributor.author |
Gil Grau, Salvador
|
es_ES |
dc.date.accessioned |
2016-03-29T10:45:14Z |
|
dc.date.available |
2016-03-29T10:45:14Z |
|
dc.date.issued |
2014-08 |
|
dc.identifier.issn |
2191-1363 |
|
dc.identifier.uri |
http://hdl.handle.net/10251/62053 |
|
dc.description.abstract |
The synthesis, characterization and sensing features of a novel
probe 1 for the selective chromogenic recognition of diisopropylfluorophosphate
(DFP), a sarin and soman mimic, in 99:1 (v/
v) water/acetonitrile and in the gas phase is reported. Colour
modulation is based on the combined reaction of phosphorylation
of 1 and fluoride-induced hydrolysis of a silyl ether
moiety. As fluoride is a specific reaction product of the reaction
between DFP and the OH group, the probe shows a selective
colour modulation in the presence of this chemical. Other
nerve agent simulants, certain anions, oxidant species and
other organophosphorous compounds were unable to induce
colour changes in 1. This is one of the very few examples of
a selective detection, in solution and in the gas phase, of
a sarin and soman simulant versus other reactive derivatives
such as the tabun mimic diethylcyanophosphate (DCNP). |
es_ES |
dc.description.sponsorship |
Financial support from the Spanish Government (Project MAT2012-38429-C04) is gratefully acknowledged. S. E. is grateful to the Generalitat Valenciana for his Santiago Grisolia fellowship. L. P. thanks the Universitat Politecnica de Valencia for his doctoral fellowship. |
en_EN |
dc.language |
Inglés |
es_ES |
dc.publisher |
Wiley Open Access |
es_ES |
dc.relation.ispartof |
ChemistryOpen |
es_ES |
dc.rights |
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) |
es_ES |
dc.subject |
chromogenic probe |
es_ES |
dc.subject |
diisopropylfluorophosphate |
es_ES |
dc.subject |
nerve agents |
es_ES |
dc.subject |
sarin |
es_ES |
dc.subject |
soman |
es_ES |
dc.subject.classification |
QUIMICA INORGANICA |
es_ES |
dc.subject.classification |
QUIMICA ORGANICA |
es_ES |
dc.title |
A Chromogenic Probe for the Selective Recognition of Sarin and Soman Mimic DFP |
es_ES |
dc.type |
Artículo |
es_ES |
dc.identifier.doi |
10.1002/open.201402014 |
|
dc.relation.projectID |
info:eu-repo/grantAgreement/MINECO//MAT2012-38429-C04-01/ES/DESARROLLO DE MATERIALES FUNCIONALIZADOS CON PUERTAS NANOSCOPICAS PARA APLICACIONES DE LIBERACION CONTROLADA Y SENSORES PARA LA DETECCION DE NITRATO AMONICO, SULFIDRICO Y CO/ |
|
dc.rights.accessRights |
Abierto |
es_ES |
dc.contributor.affiliation |
Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic |
es_ES |
dc.contributor.affiliation |
Universitat Politècnica de València. Departamento de Química - Departament de Química |
es_ES |
dc.description.bibliographicCitation |
El Sayed Shehata Nasr, S.; Pascual Vidal, L.; Agostini, A.; Martínez-Máñez, R.; Sancenón Galarza, F.; Costero Nieto, AM.; Parra Álvarez, M.... (2014). A Chromogenic Probe for the Selective Recognition of Sarin and Soman Mimic DFP. ChemistryOpen. 3(4):142-145. https://doi.org/10.1002/open.201402014 |
es_ES |
dc.description.accrualMethod |
S |
es_ES |
dc.relation.publisherversion |
http://dx.doi.org/10.1002/open.201402014 |
es_ES |
dc.description.upvformatpinicio |
142 |
es_ES |
dc.description.upvformatpfin |
145 |
es_ES |
dc.type.version |
info:eu-repo/semantics/publishedVersion |
es_ES |
dc.description.volume |
3 |
es_ES |
dc.description.issue |
4 |
es_ES |
dc.relation.senia |
276583 |
es_ES |
dc.identifier.pmid |
25478309 |
en_EN |
dc.identifier.pmcid |
PMC4232269 |
en_EN |
dc.contributor.funder |
Generalitat Valenciana |
|
dc.contributor.funder |
Universitat Politècnica de València |
|
dc.contributor.funder |
Ministerio de Economía y Competitividad |
es_ES |