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Partially oxidized gold nanoparticles: a catalytic base-free system for the aerobic homocoupling of alkynes

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Partially oxidized gold nanoparticles: a catalytic base-free system for the aerobic homocoupling of alkynes

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Boronat Zaragoza, M.; Laursen, SO.; Leyva Perez, A.; Oliver Meseguer, J.; Cómbita Merchán, DF.; Corma Canós, A. (2014). Partially oxidized gold nanoparticles: a catalytic base-free system for the aerobic homocoupling of alkynes. Journal of Catalysis. 315:6-14. doi:10.1016/j.jcat.2014.04.003

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Title: Partially oxidized gold nanoparticles: a catalytic base-free system for the aerobic homocoupling of alkynes
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
The mechanism of alkyne homocoupling over gold nanoparticles and clusters, isolated and supported on CeO2, has been theoretically investigated by means of periodic DFT calculations. The theoretical study indicates that ...[+]
Subjects: Gold , Heterogeneous catalysis , DFT , Oxidative coupling of alkynes , Reaction mechanism , C-H activation
Copyrigths: Cerrado
Source:
Journal of Catalysis. (issn: 0021-9517 ) (eissn: 1090-2694 )
DOI: 10.1016/j.jcat.2014.04.003
Publisher:
Elsevier
Publisher version: http://dx.doi.org/10.1016/j.jcat.2014.04.003
Thanks:
Financial support from Spanish MCIINN (Consolider Ingenio 2010-MULTICAT CSD2009-00050 and Subprograma de apoyo a Centros y Universidades de Excelencia Severo Ochoa SEV 2012 0267 Projects) is acknowledged. Red Espanola de ...[+]
Type: Artículo

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