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C2 symmetrical nickel complexes derived from a-amino amides as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes

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C2 symmetrical nickel complexes derived from a-amino amides as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes

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Escorihuela Fuentes, J.; Altava Benito, B.; Burguete Azcarate, MI.; Luis Lafuente, S. (2013). C2 symmetrical nickel complexes derived from a-amino amides as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes. Tetrahedron. 69(2):551-558. doi:10.1016/j.tet.2012.11.025

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Title: C2 symmetrical nickel complexes derived from a-amino amides as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes
Author:
UPV Unit: Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic
Issued date:
Abstract:
[EN] A series of C2 symmetrical 1:2 Ni:L complexes derived from a-amino amides were studied for the enantioselective addition of dialkylzinc reagents to aldehydes. Different structural elements on the ligands seem to play ...[+]
Subjects: Asymmetric catalysis , Organozinc , Amino amide , Enantioselectivity , Aldehyde
Copyrigths: Cerrado
Source:
Tetrahedron. (issn: 0040-4020 )
DOI: 10.1016/j.tet.2012.11.025
Publisher:
Elsevier
Publisher version: http://dx.doi.org/10.1016/j.tet.2012.11.025
Thanks:
This work was supported by the Spanish Ministerio de Ciencia e Innovacion (MCINN) (CTQ2009-14366-C02-02), Fundacio Caixa Castello-Bancaixa (P1-1B-2009-58) and Generalitat Valenciana PROMETEO 2012/020. The authors are ...[+]
Type: Artículo

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