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Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties

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Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties

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dc.contributor.author Kozachuk, O. es_ES
dc.contributor.author Luz Mínguez, Ignacio es_ES
dc.contributor.author Llabrés i Xamena, Francesc Xavier es_ES
dc.contributor.author Noei, H. es_ES
dc.contributor.author Kauer, M. es_ES
dc.contributor.author Albada, H.B. es_ES
dc.contributor.author Bloch, E.D. es_ES
dc.contributor.author Marler, B. es_ES
dc.contributor.author Wang, Y.M. es_ES
dc.contributor.author Muhler, M. es_ES
dc.contributor.author Fischer, R.A. es_ES
dc.date.accessioned 2016-05-10T12:55:22Z
dc.date.available 2016-05-10T12:55:22Z
dc.date.issued 2014-07
dc.identifier.issn 1433-7851
dc.identifier.uri http://hdl.handle.net/10251/63867
dc.description.abstract A mixed-linker solid-solution approach was employed to modify the metal sites and introduce structural defects into the mixed-valence Ru-II/III structural analogue of the well-known MOF family [M-3(II,II)(btc)(2)] (M= Cu, Mo, Cr, Ni, Zn; btc= benzene-1,3,5-tricarboxylate), with partly missing carboxylate ligators at the Ru-2 paddle-wheels. Incorporation of pyridine-3,5-dicarboxylate (pydc), which is the same size as btc but carries lower charge, as a second, defective linker has led to the mixed-linker isoreticular derivatives of Ru-MOF, which display characteristics unlike those of the defect-free framework. Along with the creation of additional coordinatively unsaturated sites, the incorporation of pydc induces the partial reduction of ruthenium. Accordingly, the modified Ru sites are responsible for the activity of the "defective" variants in the dissociative chemisorption of CO2, the enhanced performance in CO sorption, the formation of hydride species, and the catalytic hydrogenation of olefins. es_ES
dc.description.sponsorship O.K. acknowledges Ruhr-University Research School (http://www.research-school.rub.de) for admission and additional support of her PhD project. I. L. and F. X. L. X. acknowledge support by Consolider-Ingenio 2010 (project MULTICAT) and the "Severo Ochoa" program. en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject CO2 reduction es_ES
dc.subject Heterogeneous Catalysis es_ES
dc.subject Hydrogen splitting es_ES
dc.subject Metal-Organic Frameworks es_ES
dc.subject Structural defects es_ES
dc.title Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/anie.201311128
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ / es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Kozachuk, O.; Luz Mínguez, I.; Llabrés I Xamena, FX.; Noei, H.; Kauer, M.; Albada, H.; Bloch, E.... (2014). Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties. Angewandte Chemie International Edition. 53(27):7058-7062. https://doi.org/10.1002/anie.201311128 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/anie.201311128 es_ES
dc.description.upvformatpinicio 7058 es_ES
dc.description.upvformatpfin 7062 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 53 es_ES
dc.description.issue 27 es_ES
dc.relation.senia 268165 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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