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dc.contributor.author | Santiago Portillo, Andrea | es_ES |
dc.contributor.author | Navalón Oltra, Sergio | es_ES |
dc.contributor.author | García Cirujano, Francisco | es_ES |
dc.contributor.author | Llabrés i Xamena, Francesc Xavier | es_ES |
dc.contributor.author | Alvaro Rodríguez, Maria Mercedes | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.date.accessioned | 2016-05-12T10:10:30Z | |
dc.date.issued | 2015-06 | |
dc.identifier.issn | 2155-5435 | |
dc.identifier.uri | http://hdl.handle.net/10251/63957 | |
dc.description.abstract | Materiaux de l Institute Lavosier-101 (MIL-101) promotes benzylic oxidation of hydrocarbons exclusively by molecular oxygen in the absence of any other oxidizing reagent or initiator. Using indane as model compound, the selectivity toward the wanted ol/one mixture is higher for MIL-101(Cr) (87% selectivity at 30% conversion) than for MIL-101(Fe) (71% selectivity at 30% conversion), a fact that was associated with the preferential adsorption of indane within the pore system. Product distribution and quenching experiments with 2,2,6,6-tetramethyl-1-piperidinyloxy, benzoic acid, and dimethylformamide show that the reaction mechanism is a radical chain autoxidation of the benzylic positions by molecular oxygen, and the differences in selectivity have been attributed to the occurrence of the autoxidation process inside or outside the metal organic framework pores. MIL-101 is reusable, does not leach metals to the solution, and maintains the crystal structure during the reaction. The scope of the benzylic oxidation was expanded to other benzylic compounds including ethylbenzene, n-butylbenzene, iso-butylbenzene, 1-bromo-4-butylbenzene, sec-butylbenzene, and cumene. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) is gratefully acknowledged. Generalidad Valenciana is also thanked for funding (Prometeo 2012/013 and GV/2013/040). | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | ACS Catalysis | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Heterogeneous catalysis | es_ES |
dc.subject | Metal organic frameworks | es_ES |
dc.subject | Aerobic oxidation | es_ES |
dc.subject | MIL-101 as catalyst | es_ES |
dc.subject | Benzylic oxidation | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | MIL-101 as Reusable Solid Catalyst for Autoxidation of Benzylic Hydrocarbons in the Absence of Additional Oxidizing Reagents | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1021/acscatal.5b00411 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//GV%2F2013%2F040/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F013/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Santiago Portillo, A.; Navalón Oltra, S.; García Cirujano, F.; Llabrés I Xamena, FX.; Alvaro Rodríguez, MM.; García Gómez, H. (2015). MIL-101 as Reusable Solid Catalyst for Autoxidation of Benzylic Hydrocarbons in the Absence of Additional Oxidizing Reagents. ACS Catalysis. 5(6):3216-3224. https://doi.org/10.1021/acscatal.5b00411 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1021/acscatal.5b00411 | es_ES |
dc.description.upvformatpinicio | 3216 | es_ES |
dc.description.upvformatpfin | 3224 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 5 | es_ES |
dc.description.issue | 6 | es_ES |
dc.relation.senia | 291249 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |