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Well-Defined Noble Metal Single Sites in Zeolites as an Alternative to Catalysis by Insoluble Metal Salts

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Well-Defined Noble Metal Single Sites in Zeolites as an Alternative to Catalysis by Insoluble Metal Salts

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Rubio Marqués, P.; Rivero Crespo, MÁ.; Leyva Perez, A.; Corma Canós, A. (2015). Well-Defined Noble Metal Single Sites in Zeolites as an Alternative to Catalysis by Insoluble Metal Salts. Journal of the American Chemical Society. 137(36):11832-11837. doi:10.1021/jacs.5b07304

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Title: Well-Defined Noble Metal Single Sites in Zeolites as an Alternative to Catalysis by Insoluble Metal Salts
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
Insoluble precious metal chlorides in polymeric form (i.e., PtCl2, PdCl2, AuCl, RhCl3) are commonly used as catalysts for a plethora of organic reactions in solution. Here we show that only the minor soluble fraction of ...[+]
Subjects: HETEROGENEOUS CATALYSTS , ORGANIC-SYNTHESIS , BASIC ZEOLITES , PARTICLE-SIZE , PLATINUM , ALKYNES , PALLADIUM , ALKENES , GOLD , HYDROAMINATION , Electron Microscopy Service of the UPV
Copyrigths: Cerrado
Source:
Journal of the American Chemical Society. (issn: 0002-7863 )
DOI: 10.1021/jacs.5b07304
Publisher:
American Chemical Society
Publisher version: http://dx.doi.org/10.1021/jacs.5b07304
Thanks:
A.L.-P. thanks ITQ for a contract. P.R.-M. and M.A.R.-C. thank MEC for a FPU scholarship. We thank Dr. Angel Cantin for the preparation of three starting materials. We also thank the Electron Microscopy Service of the UPV ...[+]
Type: Artículo

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