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Mechanism of the Catalytic Gas-Phase Aldehyde Production from Trinuclear W3S4 Complexes Bearing W-OEt groups

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Mechanism of the Catalytic Gas-Phase Aldehyde Production from Trinuclear W3S4 Complexes Bearing W-OEt groups

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Beltran, TF.; Feliz Rodriguez, M.; Llusar, R.; Safont, VS.; Vicent, C. (2011). Mechanism of the Catalytic Gas-Phase Aldehyde Production from Trinuclear W3S4 Complexes Bearing W-OEt groups. Catalysis Today. 177(1):72-78. https://doi.org/10.1016/j.cattod.2011.05.017

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/64097

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Title: Mechanism of the Catalytic Gas-Phase Aldehyde Production from Trinuclear W3S4 Complexes Bearing W-OEt groups
Author: Beltran, Tomas F. Feliz Rodriguez, Marta Llusar, Rosa Safont, Vicent S. Vicent, Cristian
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] Collision induced dissociation experiments of the alkoxo [W3S4(dmpe)(2)(O)(OCH2CH3)](+) tungsten (IV) cation reveal that aldehyde elimination is the dominant reaction pathway. Complementary deuterium labelling experiments ...[+]
Subjects: Tungsten clusters , Alkoxo ligands , ESI , CID , Ion-molecule reactions , DFT calculations
Copyrigths: Cerrado
Source:
Catalysis Today. (issn: 0920-5861 )
DOI: 10.1016/j.cattod.2011.05.017
Publisher:
Elsevier
Publisher version: http://dx.doi.org/10.1016/j.cattod.2011.05.017
Project ID:
info:eu-repo/grantAgreement/MICINN//CTQ2008-02670/ES/NUEVOS ASPECTOS SOBRE LA QUIMICA DE LOS CALCOGENUROS CLUSTER DE METALES DE TRANSICION DIRIGIDOS A SUS APLICACIONES EN CATALISIS Y ELECTRONICA MOLECULAR/
...[+]
info:eu-repo/grantAgreement/MICINN//CTQ2008-02670/ES/NUEVOS ASPECTOS SOBRE LA QUIMICA DE LOS CALCOGENUROS CLUSTER DE METALES DE TRANSICION DIRIGIDOS A SUS APLICACIONES EN CATALISIS Y ELECTRONICA MOLECULAR/
MICINN/CTQ2009-14541-C02-01
Fundacio Bancaixa-UJI/ P1.1B2008-37
Fundacio Bancaixa-UJI/P1.1B2010-46
GV/ACOMP/2011/037
GV/PROMETEO/2009/053
[-]
Thanks:
The financial support of the Spanish Ministerio de Ciencia e Innovacion (research projects CTQ2008-02670 and CTQ2009-14541-C02-01), Fundacio Bancaixa-UJI (P1.1B2008-37 and P1.1B2010-46), and Generalitat Valenciana ...[+]
Type: Artículo

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