Mostrar el registro sencillo del ítem
dc.contributor.author | López Nieto, José Manuel![]() |
es_ES |
dc.contributor.author | Solsona Espriu, Benjamin Eduardo![]() |
es_ES |
dc.contributor.author | Grasselli, Robert K.![]() |
es_ES |
dc.contributor.author | Concepción Heydorn, Patricia![]() |
es_ES |
dc.date.accessioned | 2016-05-17T07:29:47Z | |
dc.date.available | 2016-05-17T07:29:47Z | |
dc.date.issued | 2014-09 | |
dc.identifier.issn | 1022-5528 | |
dc.identifier.uri | http://hdl.handle.net/10251/64186 | |
dc.description.abstract | Metal oxide promoted NiO catalysts with a Ni/(Me + Ni) atomic ratio 0.92 have been investigated for the oxidative dehydrogenation of ethane. These materials have been characterized by several techniques (N-2-adsorption, X-ray diffraction, X-ray photoelectron spectroscopy and Fourier transformed infrared spectroscopy of adsorbed CO and ethylene). The nature of surface sites is strongly influenced by the valence and the acid/base characteristics of the metal oxide promoters, which have a great impact on the selectivity to ethylene. Accordingly, a clear correlation between selectivity to ethylene and the valence of the promoter has been observed in the present work. Additionally, the acidity of the catalyst also enhances the selectivity to ethylene. | es_ES |
dc.description.sponsorship | The Spanish authors would like to thank the DGICYT in Spain (Project CTQ2012-37925-C03-1 and CTQ2012-37925-C03-2) for financial support. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Springer Verlag (Germany) | es_ES |
dc.relation.ispartof | Topics in Catalysis | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Promoted NiO catalysts | es_ES |
dc.subject | Nickel oxide | es_ES |
dc.subject | Oxidative dehydrogenation | es_ES |
dc.subject | Ethane | es_ES |
dc.subject | Ethylene | es_ES |
dc.subject | Valence | es_ES |
dc.subject | Promoters | es_ES |
dc.subject | Acidity and basicity | es_ES |
dc.title | Promoted NiO catalysts for the oxidative dehydrogenation of ethane | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1007/s11244-014-0288-2 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2012-37925-C03-01/ES/CATALIZADORES PARA LA ENERGIA Y EL MEDIOAMBIENTE: ACTIVACION SELECTIVA DE ENLACES S-H Y C-H/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2012-37925-C03-02/ES/CATALIZADORES PARA LA ENERGIA Y EL MEDIOAMBIENTE: OPTIMIZACION DE PROCESOS CATALITICOS DE OXIDACION PARA LA OBTENCION DE HIDROGENO Y OLEFINAS Y LA ELIMINACION DE VOCS./ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | López Nieto, JM.; Solsona Espriu, BE.; Grasselli, RK.; Concepción Heydorn, P. (2014). Promoted NiO catalysts for the oxidative dehydrogenation of ethane. Topics in Catalysis. 57(14-16):1248-1255. https://doi.org/10.1007/s11244-014-0288-2 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1007/s11244-014-0288-2 | es_ES |
dc.description.upvformatpinicio | 1248 | es_ES |
dc.description.upvformatpfin | 1255 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 57 | es_ES |
dc.description.issue | 14-16 | es_ES |
dc.relation.senia | 289556 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.description.references | Lippe D (2013) Oil Gas J 111:3 | es_ES |
dc.description.references | True WR (2010) Oil Gas J 108:34 | es_ES |
dc.description.references | Ren T, Patel MK, Blok K (2008) Energy 33:817 | es_ES |
dc.description.references | Cavani F, Ballarini N, Cericola A (2007) Catal Today 127:113 | es_ES |
dc.description.references | Bhasin MM (2003) Top Catal 23:145 | es_ES |
dc.description.references | Bhasin MM, McCain JH, Vora BV, Imai T, Pujadó PR (2001) Appl Catal A Gen 221:397 | es_ES |
dc.description.references | Blasco T, López Nieto JM (1997) Appl Catal A Gen 157:117 | es_ES |
dc.description.references | Bañares MA (1999) Catal Today 51:319 | es_ES |
dc.description.references | Grzybowska-Świerkosz B (2000) Top Catal 11–12:23 | es_ES |
dc.description.references | Davies TE, García T, Solsona B, Taylor SH (2006) Chem Commun 32:3417 | es_ES |
dc.description.references | Sri Hari Kumar A, Upendar K, Qiao A, Rao PSN, Lingaiah N, Kalevaru VN, Martin A, Sailu Ch, Sai Prasad PS (2013) Catal Commun 3376–3379 | es_ES |
dc.description.references | Frank B, Morassutto M, Schomacker R, Schlogl R, Sheng SuD (2010) ChemCatChem 2:644 | es_ES |
dc.description.references | Skoufa Z, Heracleous E, Lemonidou AA (2012) Catal Today 192:169 | es_ES |
dc.description.references | Heracleous E, Lee AF, Wilson K, Lemonidou AA (2005) J Catal 231:159 | es_ES |
dc.description.references | Heracleous E, Lemonidou AA (2006) J Catal 237:162 | es_ES |
dc.description.references | Heracleous E, Lemonidou AA (2010) J Catal 270:67 | es_ES |
dc.description.references | Zhu H, Ould-Chikh S, Anjum DH, Sun M, Biausque G, Basset JM, Caps V (2012) J Catal 285:292 | es_ES |
dc.description.references | Savova B, Loridant S, Filkova D, Millet JMM (2010) Appl Catal A Gen 390:148 | es_ES |
dc.description.references | Solsona B, Concepción P, Demicol B, Hernández S, Delgado JJ, Calvino JJ, López Nieto JM (2012) J Catal 295:104 | es_ES |
dc.description.references | Solsona B, Dejoz AM, Vázquez MI, Ivars F, López Nieto JM (2009) Top Catal 52:751 | es_ES |
dc.description.references | Solsona B, López Nieto JM, Concepción P, Dejoz A, Ivars F, Vázquez MI (2011) J Catal 280:28 | es_ES |
dc.description.references | Skoufa Z, Heracleous E, Lemonidou AA (2012) Chem Eng Sci 84:48 | es_ES |
dc.description.references | Lin X, Xi Y, Sun J (2012) J Phys Chem C 116:3503 | es_ES |
dc.description.references | López Nieto JM, Botella P, Vázquez MI, Dejoz A (2002) Chem Commun 17:1906 | es_ES |
dc.description.references | Solsona B, Vázquez MI, Ivars F, Dejoz A, Concepción P, López Nieto JM (2004) J Catal 252:271 | es_ES |
dc.description.references | Nguyen TT, Aouine M, Millet JMM (2012) Catal Commun 21:22 | es_ES |
dc.description.references | Ischenko EV, Andrushkevich TV, Popova GYa, Bondareva VM, Chesalov YA, Kardash TYu, Plyasova LM, Dovlitova LS, Ischenko AV (2010) Stud Surf Sci Catal 175:479 | es_ES |
dc.description.references | Choudhary TV, Banerjee S, Choudhary VR (2002) Appl Catal A Gen 234:1 | es_ES |
dc.description.references | Bortolozzi JP, Gutierrez LB, Ulla MA (2013) Appl Catal A Gen 452:179 | es_ES |
dc.description.references | Concepción P, López Nieto JM, Pérez-Pariente J (1994) Catal Lett 28:9 | es_ES |
dc.description.references | Kao CY, Huang KT, Wan BZ (1994) Ind Eng Chem Res 33:2066 | es_ES |
dc.description.references | Galli A, López Nieto JM, Dejoz A, Vázquez MI (1995) Catal Lett 34:51 | es_ES |
dc.description.references | Heracleous E, Machli M, Lemonidou AA, Vasalos IA (2005) J Mol Catal A Chem 232:29 | es_ES |
dc.description.references | Scarano D, Spoto G, Bordiga S, Carnelli L, Ricchiardi G, Zecchina A (1994) Langmuir 10:3094 | es_ES |