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dc.contributor.author | Correia, Daniela M. | es_ES |
dc.contributor.author | Ribeiro, Clarisse | es_ES |
dc.contributor.author | Ferreira, Jose C. C. | es_ES |
dc.contributor.author | Botelho, Gabriela | es_ES |
dc.contributor.author | Gómez Ribelles, José Luís | es_ES |
dc.contributor.author | Lanceros Mendez, Senen | es_ES |
dc.contributor.author | Sencadas, Vitor | es_ES |
dc.date.accessioned | 2016-05-17T09:14:06Z | |
dc.date.available | 2016-05-17T09:14:06Z | |
dc.date.issued | 2014-07 | |
dc.identifier.issn | 0032-3888 | |
dc.identifier.uri | http://hdl.handle.net/10251/64208 | |
dc.description.abstract | Poly(hydroxybutyrate) (PHB) obtained from sugar cane waste was dissolved in a blend of chloroform and dimethylformamide (DMF) and electrospun at 40 degrees C. By adding DMF to the solution, the electrospinning process for the PHB polymer becomes more stable, allowing complete polymer crystallization during the jet travelling between the tip and the grounded collector. The influence of processing parameters on fiber size and distribution was systematically studied. It was observed that an increase of tip inner diameter promotes a decrease of the fiber average size and a broader distribution. Conversely, an increase of the electric field and flow rate produces an increase of fiber diameter until a maximum of similar to 2.0 mu m but for electric fields higher than 1.5 kV cm(-1), a decrease of the fiber diameter was observed. Polymer crystalline phase seems to be independent of the processing conditions and a crystallinity degree of 53% was found. Moreover, thermal degradation of the as-spun membrane occurs in single step degradation with activation energy of 91 kJ mol(-1). Furthermore, MC-3T3-E1 cell adhesion was not inhibited by the fiber mats preparation, indicating their potential use for biomedical applications. | es_ES |
dc.description.sponsorship | Contract grant sponsor: FEDER; contract grant sponsor: Programa Operacional Factores de Competitividade-COMPETE; contract grant sponsor: FCT-Fundacao para a Ciencia e a Tecnologia; contract grant numbers: NANO/NMed-SD/0156/2007, PTDC/CTM/73030/2006, and PTDC/CTM/69316/2006; contract grant sponsor: COST Action MP1003, 2010 'European Scientific Network for Artificial Muscles'; contract grant sponsor: FCT; contract grant numbers: SFRH/BPD/63148/2009 and SFRH/BD/82411/2011; contract grant sponsor: IINL; contract grant sponsor: Spanish Ministry of Science and Innovation (including the FEDER financial support); contract grant number: MAT2010-21611-C03-01; contract grant sponsors: VI National R&D&i Plan 2008-2011, Iniciativa Ingenio 2010, Consolider Program, and Instituto de Salud Carlos III (with assistance from the European Regional Development Fund). | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Wiley | es_ES |
dc.relation.ispartof | Polymer Engineering and Science | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | THERMOGRAVIMETRIC DATA | es_ES |
dc.subject | POLYHYDROXYBUTYRATE | es_ES |
dc.subject | MORPHOLOGY | es_ES |
dc.subject | SCAFFOLDS | es_ES |
dc.subject | BLENDS | es_ES |
dc.subject | POLY(3-HYDROXYBUTYRATE) | es_ES |
dc.subject | MATS | es_ES |
dc.subject | POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYVALERATE) | es_ES |
dc.subject | POLYHYDROXYALKANOATES | es_ES |
dc.subject | BIOCOMPATIBILITY | es_ES |
dc.subject.classification | MAQUINAS Y MOTORES TERMICOS | es_ES |
dc.title | Influence of electrospinning parameters on Poly(hydroxybutyrate) electrospun membranes fiber size and distribution | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/pen.23704 | |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT/SFRH/SFRH/BPD/63148/2009/PT/ | en_EN |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT/SFRH/SFRH/BD/82411/2011/PT/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/COST//MP1003/EU/European Scientific Network for Artificial Muscles (ESNAM)/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT/5876-PPCDTI/109368/PT/“Smart joint implants using bionanocomposites-(SIMBIO)”/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//MAT2010-21611-C03-01/ES/MATERIALES BIOESTABLES Y BIOREABSORBIBLES A LARGO PLAZO COMO SOPORTES MACROPOROSOS PARA LA REGENERACION DEL CARTILAGO ARTICULAR/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT/5876-PPCDTI/73030/PT/Polarization-driven self-assembly of organic and biomaterials using ferroelectric polymers/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT/5876-PPCDTI/69316/PT/Multiferroic, magnetoelectric and metallic micro and nanocomposites based on electroactive polymers for advanced applications/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT/POCI/39723/PT/Component Technology Software Applied to Power Systems/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Centro de Biomateriales e Ingeniería Tisular - Centre de Biomaterials i Enginyeria Tissular | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada | es_ES |
dc.description.bibliographicCitation | Correia, DM.; Ribeiro, C.; Ferreira, JCC.; Botelho, G.; Gómez Ribelles, JL.; Lanceros Mendez, S.; Sencadas, V. (2014). Influence of electrospinning parameters on Poly(hydroxybutyrate) electrospun membranes fiber size and distribution. Polymer Engineering and Science. 54(7):1608-1617. https://doi.org/10.1002/pen.23704 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/pen.23704 | es_ES |
dc.description.upvformatpinicio | 1608 | es_ES |
dc.description.upvformatpfin | 1617 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 54 | es_ES |
dc.description.issue | 7 | es_ES |
dc.relation.senia | 284982 | es_ES |
dc.identifier.eissn | 1548-2634 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | European Cooperation in Science and Technology | es_ES |
dc.contributor.funder | Instituto de Salud Carlos III | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |
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