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dc.contributor.author | Valente, J.S. | es_ES |
dc.contributor.author | Quintana-Solorzano, R. | es_ES |
dc.contributor.author | Armendariz-Herrera, H. | es_ES |
dc.contributor.author | Barragan-Rodriguez, G. | es_ES |
dc.contributor.author | López Nieto, José Manuel | es_ES |
dc.date.accessioned | 2016-05-17T09:21:43Z | |
dc.date.issued | 2014-02-05 | |
dc.identifier.issn | 0888-5885 | |
dc.identifier.uri | http://hdl.handle.net/10251/64212 | |
dc.description | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Industrial & Engineering Chemistry Research, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [insert ACS Articles on Request author-directed link to Published Work, see http://doi.org/10.1021/ie402447h | |
dc.description.abstract | [EN] A MoVTeNb multimetallic mixed oxide was studied for the oxidative dehydrogenation of ethane, a promising alternative for catalytic ethylene production. Lab-scale steady-state experimental reaction data were obtained according to a 3(k) experimental design to investigate the simultaneous effect of temperature (400-480 degrees C) and space time [23-70 g(cat) h (mol of ethane) I]. A fixed-bed reactor at atmospheric pressure was employed, feeding a mixture of ethane, oxygen, and nitrogen. Ethane conversion varied from 17 to 85%, whereas selectivity for ethylene and COx varied from 94 to 76% and from 4.0 to 24%, respectively. These types of analyses are useful for determining the optimum reaction conditions to enhance the catalytic performance of the mixed oxides presented herein. | es_ES |
dc.description.sponsorship | This work was financially supported by the Instituto Mexicano del Petroleo. Technical support from Eng. G. Alonso-Ramirez is gratefully acknowledged. | |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | Industrial and Engineering Chemistry Research | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Mo-V-Te-Nb | es_ES |
dc.subject | Oxides | es_ES |
dc.subject | Ethane oxidative dehydrogenation | es_ES |
dc.subject | Kinetic study | es_ES |
dc.title | Kinetic Study of Oxidative Dehydrogenation of Ethane over MoVTeNb Mixed-Oxide Catalyst | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1021/ie402447h | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Valente, J.; Quintana-Solorzano, R.; Armendariz-Herrera, H.; Barragan-Rodriguez, G.; López Nieto, JM. (2014). Kinetic Study of Oxidative Dehydrogenation of Ethane over MoVTeNb Mixed-Oxide Catalyst. Industrial and Engineering Chemistry Research. 53(5):1775-1786. doi:10.1021/ie402447h | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1021/ie402447h | es_ES |
dc.description.upvformatpinicio | 1775 | es_ES |
dc.description.upvformatpfin | 1786 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 53 | es_ES |
dc.description.issue | 5 | es_ES |
dc.relation.senia | 258593 | es_ES |
dc.contributor.funder | Instituto Mexicano del Petróleo |