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Kinetic Study of Oxidative Dehydrogenation of Ethane over MoVTeNb Mixed-Oxide Catalyst

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Kinetic Study of Oxidative Dehydrogenation of Ethane over MoVTeNb Mixed-Oxide Catalyst

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dc.contributor.author Valente, J.S. es_ES
dc.contributor.author Quintana-Solorzano, R. es_ES
dc.contributor.author Armendariz-Herrera, H. es_ES
dc.contributor.author Barragan-Rodriguez, G. es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2016-05-17T09:21:43Z
dc.date.issued 2014-02-05
dc.identifier.issn 0888-5885
dc.identifier.uri http://hdl.handle.net/10251/64212
dc.description This document is the Accepted Manuscript version of a Published Work that appeared in final form in Industrial & Engineering Chemistry Research, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [insert ACS Articles on Request author-directed link to Published Work, see http://doi.org/10.1021/ie402447h
dc.description.abstract [EN] A MoVTeNb multimetallic mixed oxide was studied for the oxidative dehydrogenation of ethane, a promising alternative for catalytic ethylene production. Lab-scale steady-state experimental reaction data were obtained according to a 3(k) experimental design to investigate the simultaneous effect of temperature (400-480 degrees C) and space time [23-70 g(cat) h (mol of ethane) I]. A fixed-bed reactor at atmospheric pressure was employed, feeding a mixture of ethane, oxygen, and nitrogen. Ethane conversion varied from 17 to 85%, whereas selectivity for ethylene and COx varied from 94 to 76% and from 4.0 to 24%, respectively. These types of analyses are useful for determining the optimum reaction conditions to enhance the catalytic performance of the mixed oxides presented herein. es_ES
dc.description.sponsorship This work was financially supported by the Instituto Mexicano del Petroleo. Technical support from Eng. G. Alonso-Ramirez is gratefully acknowledged.
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Industrial and Engineering Chemistry Research es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Mo-V-Te-Nb es_ES
dc.subject Oxides es_ES
dc.subject Ethane oxidative dehydrogenation es_ES
dc.subject Kinetic study es_ES
dc.title Kinetic Study of Oxidative Dehydrogenation of Ethane over MoVTeNb Mixed-Oxide Catalyst es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/ie402447h
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Valente, J.; Quintana-Solorzano, R.; Armendariz-Herrera, H.; Barragan-Rodriguez, G.; López Nieto, JM. (2014). Kinetic Study of Oxidative Dehydrogenation of Ethane over MoVTeNb Mixed-Oxide Catalyst. Industrial and Engineering Chemistry Research. 53(5):1775-1786. doi:10.1021/ie402447h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1021/ie402447h es_ES
dc.description.upvformatpinicio 1775 es_ES
dc.description.upvformatpfin 1786 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 53 es_ES
dc.description.issue 5 es_ES
dc.relation.senia 258593 es_ES
dc.contributor.funder Instituto Mexicano del Petróleo


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