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Thermal-mechanical behaviour of chitosan-cellulose derivative thermoreversible hydrogel films

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Thermal-mechanical behaviour of chitosan-cellulose derivative thermoreversible hydrogel films

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dc.contributor.author Cerqueira Barros, Sandra es_ES
dc.contributor.author Alves da Silva, Ana es_ES
dc.contributor.author Barbosa Costa, Diana es_ES
dc.contributor.author Costa, Carlos M es_ES
dc.contributor.author Lanceros-Mendez, Senentxu es_ES
dc.contributor.author Tamano Maciavello, M.N. es_ES
dc.contributor.author Gómez Ribelles, José Luís es_ES
dc.contributor.author Sentanin, Franciani es_ES
dc.contributor.author Pawlicka, Agnieszka es_ES
dc.contributor.author Silva, Maria Manuela es_ES
dc.date.accessioned 2016-06-02T08:42:21Z
dc.date.available 2016-06-02T08:42:21Z
dc.date.issued 2015-06
dc.identifier.issn 0969-0239
dc.identifier.uri http://hdl.handle.net/10251/65085
dc.description.abstract Hydrogels are high water content materials prepared by polymer crosslinking that are able to release active species, such as therapeutic, antibacterial, antiperspirant and moisturising agents, and fragrances. In recent years, several hydrogel systems have been reported based on both natural and synthetic polymers. Among the natural polymers, chitosan and cellulose-derivatives have been extensively studied, due to their stimuli responsive properties (pH and temperature sensitivity, respectively). In this work, we have developed physically crosslinked hydrogel films based on chitosan (CH) and (hydroxypropyl)methyl cellulose (HPMC). These films were prepared by two methodologies: solvent casting and freeze thaw techniques. The resulting membranes, were assessed in terms of thermal (DSC and TGA), mechanical (stress strain mechanical assays and DMA) and structural (X-ray) properties. The obtained results indicate that the developed CH:HPMC membranes show a good compatibility between the two component biopolymers. Additionally, these materials display an excellent thermal stability (having a T-Decomposition > 270 degrees C), good mechanical properties (especially for the compositions with similar contents of both polymers), a glass transition temperature (T-g) higher than 194 degrees C and predominate amorphous character. The described characteristics turn the designed CH:HPMC membranes suitable candidates as active species carriers, for the envisaged textile application. es_ES
dc.description.sponsorship The authors are thankful to the Chemistry and Physic Centres at Minho University (Pest-C/QUI/UI0686/2013 and PEST-C/FIS/UI607/2013), CNPq, FAPESP and CAPES for the financial support of this research. Sandra Cerqueira Barros and Carlos M. Costa acknowledge the Portuguese Foundation for Science and Technology for the Post-Doc and Ph.D. grants provided (SFRH/BPD/85399/2012 and SFRH/BD/68499/2010) and M. M. Silva acknowledges to CNPq, for the mobility grant provided by this institution. The authors of this paper are grateful to the Company Devan-Micropolis, S.A., for the material support, namely the natural polymers chitosan (CH) and (hydroxypropyl)methyl cellulose (HPMC) employed in this study. en_EN
dc.language Inglés es_ES
dc.publisher Springer es_ES
dc.relation.ispartof Cellulose es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Chitosan es_ES
dc.subject (Hydroxypropyl)methyl cellulose es_ES
dc.subject Thermal analysis es_ES
dc.subject Rheological studies es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Thermal-mechanical behaviour of chitosan-cellulose derivative thermoreversible hydrogel films es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10570-015-0603-5
dc.relation.projectID info:eu-repo/grantAgreement/Uminho//Pest-C/QUI/UI0686/2013/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/COMPETE/132974/PT/Strategic Project - UI 607 - 2013-2014/ en_EN
dc.relation.projectID info:eu-repo/grantAgreement/Uminho//PEST-C/FIS/UI607/2013/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/COMPETE/132953/PT/Strategic Project - UI 686 - 2013-2014/
dc.relation.projectID info:eu-repo/grantAgreement/FCT//SFRH/BPD/85399/2012/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/SFRH/BPD/85399/2012/PT/
dc.relation.projectID info:eu-repo/grantAgreement/FCT//SFRH/BD/68499/2010/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/SFRH/BD/68499/2010/PT/
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Centro de Biomateriales e Ingeniería Tisular - Centre de Biomaterials i Enginyeria Tissular es_ES
dc.description.bibliographicCitation Cerqueira Barros, S.; Alves Da Silva, A.; Barbosa Costa, D.; Costa, CM.; Lanceros-Mendez, S.; Tamano Maciavello, M.; Gómez Ribelles, JL.... (2015). Thermal-mechanical behaviour of chitosan-cellulose derivative thermoreversible hydrogel films. Cellulose. 22(3):1911-1929. https://doi.org/10.1007/s10570-015-0603-5 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10570-015-0603-5 es_ES
dc.description.upvformatpinicio 1911 es_ES
dc.description.upvformatpfin 1929 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 22 es_ES
dc.description.issue 3 es_ES
dc.relation.senia 299925 es_ES
dc.identifier.eissn 1572-882X
dc.contributor.funder Universidade do Minho
dc.contributor.funder Fundação para a Ciência e a Tecnologia, Portugal
dc.contributor.funder Conselho Nacional de Desenvolvimento Científico e Tecnológico, Brasil
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