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Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions

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Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions

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Oliver Meseguer, J.; Liu, L.; Garcia Garcia, S.; Canós Giménez, C.; Domínguez Pérez, I.; Gavara Clemente, R.; Domenech Carbo, A.... (2015). Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions. Journal of the American Chemical Society. 137(11):3894-3900. doi:10.1021/jacs.5b00222.

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/65695

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Título: Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions
Autor:
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Tecnología de Alimentos - Departament de Tecnologia d'Aliments
Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
[EN] Sub-nanometric Cu clusters formed by endogenous reduction of Cu salts and Cu nanoparticles are active and selective catalysts for C−N, C−C, C−O, C−S, and C−P bond-forming reactions. Sub-nanometric Cu clusters ...[+]
Palabras clave: CROSS-COUPLING REACTIONS , HETEROGENEOUS CATALYSIS , GOLD CLUSTERS , ARYL HALIDES , DIAMINE LIGANDS , COPPER CLUSTERS , ULLMANN , TEMPERATURE , MECHANISMS , Oxidation
Derechos de uso: Cerrado
Fuente:
Journal of the American Chemical Society. (issn: 0002-7863 )
DOI: 10.1021/jacs.5b00222
Editorial:
American Chemical Society
Versión del editor: https://dx.doi.org/10.1021/jacs.5b00222
Descripción: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [insert ACS Articles on Request author-directed link to Published Work, see http://pubs.acs.org/doi/abs/10.1021%2Fjacs.5b00222 Additional Figures S1−S20, experimental procedures, and compound characterization, including NMR spectra. This material is available free of charge via the Internet at http:// pubs.acs.org.
Patrocinador:
ITQ Universitat Politècnica de València - CSIC
Spanish Ministry of Science and Innovation AGL-2012-39920-C03-01
MCIINN PLE2009
Consolider-Ingenio 2010 (proyecto MULTICAT) MCIINN
CSIC (JAE-DOC)
Tipo: Artículo

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