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Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions

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Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions

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Oliver Meseguer, J.; Liu, L.; García García, S.; Canós Giménez, C.; Domínguez Pérez, I.; Gavara Clemente, R.; Domenech Carbo, A.... (2015). Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions. Journal of the American Chemical Society. 137(11):3894-3900. https://doi.org/10.1021/jacs.5b00222

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Title: Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions
Author: Oliver Meseguer, Judit Liu, Lichen García García, Saray Canós Giménez, Clàudia Domínguez Pérez, Irene GAVARA CLEMENTE, RAFAEL Domenech Carbo, Antonio Concepción Heydorn, Patricia Leyva Perez, Antonio Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Tecnología de Alimentos - Departament de Tecnologia d'Aliments
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] Sub-nanometric Cu clusters formed by endogenous reduction of Cu salts and Cu nanoparticles are active and selective catalysts for C−N, C−C, C−O, C−S, and C−P bond-forming reactions. Sub-nanometric Cu clusters ...[+]
Subjects: CROSS-COUPLING REACTIONS , HETEROGENEOUS CATALYSIS , GOLD CLUSTERS , ARYL HALIDES , DIAMINE LIGANDS , COPPER CLUSTERS , ULLMANN , TEMPERATURE , MECHANISMS , Oxidation
Copyrigths: Cerrado
Source:
Journal of the American Chemical Society. (issn: 0002-7863 )
DOI: 10.1021/jacs.5b00222
Publisher:
American Chemical Society
Publisher version: https://dx.doi.org/10.1021/jacs.5b00222
Project ID:
info:eu-repo/grantAgreement/MINECO//AGL2012-39920-C03-01/ES/NUEVOS SISTEMAS POLIMERICOS ACTIVOS PARA EL ENVASADO DE ALIMENTOS SENSIBLES AL DETERIORO MICROBIOLOGICO Y OXIDATIVO/
info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ /
Description: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [insert ACS Articles on Request author-directed link to Published Work, see http://pubs.acs.org/doi/abs/10.1021%2Fjacs.5b00222 Additional Figures S1−S20, experimental procedures, and compound characterization, including NMR spectra. This material is available free of charge via the Internet at http:// pubs.acs.org.
Thanks:
Financial support by the Severo-Ochoa program, Consolider-Ingenio 2010 (proyecto MULTICAT), and PLE2009 project from MCIINN is acknowledged. J.O.-M., L.-L., and A.L.-P. thank ITQ for the concession of a contract. I.D. and ...[+]
Type: Artículo

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