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dc.contributor.author | Carenco, Sophie | es_ES |
dc.contributor.author | Leyva Perez, Antonio | es_ES |
dc.contributor.author | Concepción Heydorn, Patricia | es_ES |
dc.contributor.author | Boissiere, Cedric | es_ES |
dc.contributor.author | Mezailles, Nicolas | es_ES |
dc.contributor.author | Sanchez, Clement | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2016-06-13T07:17:31Z | |
dc.date.available | 2016-06-13T07:17:31Z | |
dc.date.issued | 2012-02 | |
dc.identifier.issn | 1748-0132 | |
dc.identifier.uri | http://hdl.handle.net/10251/65702 | |
dc.description.abstract | [EN] Well-defined 25 nm nickel phosphide nanoparticles act as a colloidal catalyst for the chemoselective hydrogenation of terminal and internal alkynes. Cis-alkenes are obtained in mild conditions with good conversion and selectivity. The phosphorus inserted in the Ni-P nanoparticles is critical for the selectivity of the nanocatalyst. Mechanistic investigations using isotope labeling provide insight on the reactants interaction with the nanoparticles surface. They pinpoint the occurrence of C-H bond cleavage in terminal alkynes during the reaction. (C) 2012 Elsevier Ltd. All rights reserved. | es_ES |
dc.description.sponsorship | The DGA, the Ecole Polytechnique, the CNRS and the UPMC are acknowledged for financial support. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Nano Today | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Nanocatalysis | es_ES |
dc.subject | Chemoselective hydrogenation | es_ES |
dc.subject | Nickel phosphide | es_ES |
dc.subject | Alkynes hydrogenation | es_ES |
dc.subject | Core-shell nanoparticles | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Nickel phosphide nanocatalysts for the chemoselective hydrogenation of alkynes | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.nantod.2011.12.003 | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Carenco, S.; Leyva Perez, A.; Concepción Heydorn, P.; Boissiere, C.; Mezailles, N.; Sanchez, C.; Corma Canós, A. (2012). Nickel phosphide nanocatalysts for the chemoselective hydrogenation of alkynes. Nano Today. 7:21-28. doi:10.1016/j.nantod.2011.12.003 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://dx.doi.org/10.1016/j.nantod.2011.12.003 | es_ES |
dc.description.upvformatpinicio | 21 | es_ES |
dc.description.upvformatpfin | 28 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 7 | es_ES |
dc.relation.senia | 220571 | es_ES |
dc.contributor.funder | Centre National de la Recherche Scientifique, Francia | es_ES |
dc.contributor.funder | Université Pierre et Marie Curie | es_ES |