- -

Metal-organic frameworks as heterogeneous catalysts for oxidation reactions

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

Metal-organic frameworks as heterogeneous catalysts for oxidation reactions

Show simple item record

Files in this item

dc.contributor.author Amarajothi, Dhakshina Moorthy es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2016-06-20T09:10:06Z
dc.date.available 2016-06-20T09:10:06Z
dc.date.issued 2011
dc.identifier.issn 2044-4753
dc.identifier.uri http://hdl.handle.net/10251/66158
dc.description.abstract In this Perspective, we describe the use of metal-organic frameworks (MOFs) as heterogeneous catalysts for oxidations using hydroperoxides or molecular oxygen. These two types of oxidants fulfill the requirements of green chemistry in terms of environmental benignity and sustainability. For the sake of clarity and to illustrate the possibilities of using MOFs as oxidation catalysts, we have constrained ourselves to present the results obtained for the oxidation of cycloalkanes, oxidation of benzylic positions, oxidation of cycloalkenes and aerobic oxidation of alcohols. The use of MOFs as catalysts for enantioselective oxidations has been dealt with in a separate section in which the peculiarity of the required oxidants and the advantages of having homo chiral MOFs have been discussed. The key features of MOFs as catalysts, the similarities with inorganic porous solids and future developments in this field have been discussed in separate sections. es_ES
dc.description.sponsorship Financial support by the Spanish DGI (CTQ2009-11587 and CTQ2010-18671 and Consolider MULTICAT) is gratefully acknowledged. Funding of European Commission through an integrated project (MACADEMIA) is also acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation Spanish DGI CTQ2009-11587 CTQ2010-18671 Consolider MULTICAT es_ES
dc.relation European Commission es_ES
dc.relation.ispartof Catalysis Science and Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject POROUS COORDINATION POLYMERS es_ES
dc.subject SUPPORTED GOLD NANOPARTICLES es_ES
dc.subject AEROBIC OXIDATION es_ES
dc.subject ASYMMETRIC EPOXIDATION es_ES
dc.subject ALKENE EPOXIDATION es_ES
dc.subject HYDROGEN-PEROXIDE es_ES
dc.subject SHAPE-SELECTIVITY es_ES
dc.subject ALCOHOLS es_ES
dc.subject ZEOLITE es_ES
dc.subject DESIGN es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Metal-organic frameworks as heterogeneous catalysts for oxidation reactions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c1cy00068c
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Amarajothi, DM.; Alvaro Rodríguez, MM.; García Gómez, H. (2011). Metal-organic frameworks as heterogeneous catalysts for oxidation reactions. Catalysis Science and Technology. 1(6):856-867. doi:10.1039/c1cy00068c es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c1cy00068c es_ES
dc.description.upvformatpinicio 856 es_ES
dc.description.upvformatpfin 867 es_ES
dc.type.version info:eu repo/semantics/publishedVersion es_ES
dc.description.volume 1 es_ES
dc.description.issue 6 es_ES
dc.relation.senia 215906 es_ES


This item appears in the following Collection(s)

Show simple item record