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Catalytic stereoselective addition to alkynes. Borylation or silylation promoted by magnesia-supported iron oxide and cis-diboronation or silaboration by supported platinum nanoparticles

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Catalytic stereoselective addition to alkynes. Borylation or silylation promoted by magnesia-supported iron oxide and cis-diboronation or silaboration by supported platinum nanoparticles

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Khan, A.; Asiri, AM.; Kosa, SA.; García Gómez, H.; Grirrane, A. (2015). Catalytic stereoselective addition to alkynes. Borylation or silylation promoted by magnesia-supported iron oxide and cis-diboronation or silaboration by supported platinum nanoparticles. Journal of Catalysis. 329:401-412. doi:10.1016/j.jcat.2015.05.006

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Título: Catalytic stereoselective addition to alkynes. Borylation or silylation promoted by magnesia-supported iron oxide and cis-diboronation or silaboration by supported platinum nanoparticles
Autor:
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
Iron oxide nanoparticles supported on magnesia (FeO/MgO) have been prepared by NaBH4 reduction of Fe(SO4) on MgO and spontaneous reoxidation upon storage. XPS of FeO/MgO indicates the presence of Fe(0) (16%) and Fe(II) ...[+]
Palabras clave: Heterogeneous catalysis , Iron nanoparticles as catalysts , Alkyne additions , Stereoselective additions to C-C multiple bonds
Derechos de uso: Reserva de todos los derechos
Fuente:
Journal of Catalysis. (issn: 0021-9517 ) (eissn: 1090-2694 )
DOI: 10.1016/j.jcat.2015.05.006
Editorial:
Elsevier
Versión del editor: http://dx.doi.org/10.1016/j.jcat.2015.05.006
Agradecimientos:
Financial support by the Spanish Ministry of the Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and the Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. This work was also funded by the ...[+]
Tipo: Artículo

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