Yardimci, D.; Serna Merino, PM.; Gates, BC. (2013). Surface-Mediated Synthesis of Dimeric Rhodium Catalysts on MgO: Tracking Changes in the Nuclearity and Ligand Environment of the Catalytically Active Sites by X-ray Absorption and Infrared Spectroscopies. Chemistry - A European Journal. 19(4):1235-1245. https://doi.org/10.1002/chem.201202514
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Title: | Surface-Mediated Synthesis of Dimeric Rhodium Catalysts on MgO: Tracking Changes in the Nuclearity and Ligand Environment of the Catalytically Active Sites by X-ray Absorption and Infrared Spectroscopies | |
Author: | Yardimci, Dicle Serna Merino, Pedro Manuel Gates, Bruce C. | |
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[EN] The preparation of dinuclear rhodium clusters and their use as catalysts is challenging because these clusters are unstable, evolving readily into species with higher nuclearities. We now present a novel synthetic ...[+]
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Copyrigths: | Cerrado | |
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Publisher version: | http://dx.doi.org/10.1002/chem.201202514 | |
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The research was supported by the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement no. PIOF-GA-2009-253129 (P. S.) and by DOE Basic Energy Sciences (Contract No. FG02-04ER15513) (D.Y.). We ...[+]
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