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Surface-Mediated Synthesis of Dimeric Rhodium Catalysts on MgO: Tracking Changes in the Nuclearity and Ligand Environment of the Catalytically Active Sites by X-ray Absorption and Infrared Spectroscopies

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Surface-Mediated Synthesis of Dimeric Rhodium Catalysts on MgO: Tracking Changes in the Nuclearity and Ligand Environment of the Catalytically Active Sites by X-ray Absorption and Infrared Spectroscopies

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Yardimci, D.; Serna Merino, PM.; Gates, BC. (2013). Surface-Mediated Synthesis of Dimeric Rhodium Catalysts on MgO: Tracking Changes in the Nuclearity and Ligand Environment of the Catalytically Active Sites by X-ray Absorption and Infrared Spectroscopies. Chemistry - A European Journal. 19(4):1235-1245. doi:10.1002/chem.201202514

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Título: Surface-Mediated Synthesis of Dimeric Rhodium Catalysts on MgO: Tracking Changes in the Nuclearity and Ligand Environment of the Catalytically Active Sites by X-ray Absorption and Infrared Spectroscopies
Autor:
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Fecha difusión:
Resumen:
The preparation of dinuclear rhodium clusters and their use as catalysts is challenging because these clusters are unstable, evolving readily into species with higher nuclearities. We now present a novel synthetic route ...[+]
Palabras clave: Catalysis , Cluster compounds , Dimerization , Hydrogenation , Rhodium , Supported catalysts
Derechos de uso: Cerrado
Fuente:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201202514
Editorial:
Wiley
Versión del editor: http://dx.doi.org/10.1002/chem.201202514
Tipo: Artículo

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