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From Mono- to Poly-Substituted Frameworks: A Way of Tuning the Acidic Character of C-c-H in o-Carborane Derivatives

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From Mono- to Poly-Substituted Frameworks: A Way of Tuning the Acidic Character of C-c-H in o-Carborane Derivatives

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Puga, AV.; Teixidor, F.; Sillanpaa, R.; Kivekas, R.; Arca, M.; Barbera, G.; Viñas, C. (2009). From Mono- to Poly-Substituted Frameworks: A Way of Tuning the Acidic Character of C-c-H in o-Carborane Derivatives. Chemistry - A European Journal. 15(38):9755-9763. doi:10.1002/chem.200900925

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Title: From Mono- to Poly-Substituted Frameworks: A Way of Tuning the Acidic Character of C-c-H in o-Carborane Derivatives
Author:
Issued date:
Abstract:
[EN] The incorporation of iodine atoms onto the boron vertices of the o-carborane framework causes, according to spectroscopic data, a uniform increase in the acidic character of the C-c-H (C-c= cluster carbon) vertices, ...[+]
Subjects: Boron , Carboranes , Density functional calculations , Iodine , Natural bond orbital charges
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.200900925
Publisher:
Wiley
Publisher version: http://dx.doi.org/10.1002/chem.200900925
Thanks:
This work was supported by CICYT (project MAT2006-05339), Generalitat de Catalunya (2005/SGR/00709).
Type: Artículo

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