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Pressure-induced amorphization of YVO4:Eu3+ nanoboxes

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Pressure-induced amorphization of YVO4:Eu3+ nanoboxes

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dc.contributor.author Ruiz Fuertes, Javier es_ES
dc.contributor.author Gomis, O. es_ES
dc.contributor.author León Luis, S. F. es_ES
dc.contributor.author Schrodt, N. es_ES
dc.contributor.author Manjón Herrera, Francisco Javier es_ES
dc.contributor.author Ray, Sudeshna es_ES
dc.contributor.author Santamaría Pérez, David es_ES
dc.contributor.author Sans Tresserras, Juan Ángel es_ES
dc.contributor.author Ortiz, H. M. es_ES
dc.contributor.author Errandonea, Daniel es_ES
dc.contributor.author Ferrer Roca, Chantal es_ES
dc.contributor.author Segura, A. es_ES
dc.contributor.author Martínez García, Domingo es_ES
dc.contributor.author Lavin, V. es_ES
dc.contributor.author Rodríguez Mendoza, U. R. es_ES
dc.contributor.author Muñoz, A. es_ES
dc.date.accessioned 2016-07-05T09:48:35Z
dc.date.available 2016-07-05T09:48:35Z
dc.date.issued 2016-01-15
dc.identifier.issn 0957-4484
dc.identifier.uri http://hdl.handle.net/10251/67090
dc.description This is an author-created, un-copyedited version of an article published in Nanotechnology. IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at http://dx.doi.org/10.1088/0957-4484/27/2/025701 es_ES
dc.description.abstract A structural transformation from the zircon-type structure to an amorphous phase has been found in YVO4:Eu3+ nanoboxes at high pressures above 12.7 GPa by means of x-ray diffraction measurements. However, the pair distribution function of the high-pressure phase shows that the local structure of the amorphous phase is similar to the scheelite-type YVO4. These results are confirmed both by Raman spectroscopy and Eu3+ photoluminescence which detect the phase transition to a scheelite-type structure at 10.1 and 9.1 GPa, respectively. The irreversibility of the phase transition is observed with the three techniques after a maximum pressure in the upstroke of around 20 GPa. The existence of two D-5(0)-> F-7(0) photoluminescence peaks confirms the existence of two local environments for Eu3+, at least for the low-pressure phase. One environment is the expected for substituting Y3+ and the other is likely a disordered environment possibly found at the surface of the nanoboxes. es_ES
dc.description.sponsorship This work has been performed under financial support from Spanish MINECO under the National Program of Materials (MAT2013-46649-C4-1/2/3/4-P) and the Consolider-Ingenio 2010 Program (MALTA CSD2007-00045). Funding by the Fundacion Caja Canarias (ENER-01) and the EU-FEDER funds is also acknowledged. JR-F thanks the Alexander von Humboldt Foundation for a postdoctoral fellowship and NS thanks the German Research Foundation (DFG) for financial support (Project RA2585/1-1). We acknowledge Diamond Light Source for time on beamline I15 under proposals EE3652 and EE6517. Parts of this research were carried out at the light source PETRA III at DESY (Hamburg), a member of the Helmholtz Association (HFG). We would like to thank H-P Liermann and W Morgenroth for assistance in using beamline P02.2. en_EN
dc.language Inglés es_ES
dc.publisher IOP Publishing: Hybrid Open Access es_ES
dc.relation.ispartof Nanotechnology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject High pressure es_ES
dc.subject Amorphization es_ES
dc.subject Nanocrystal es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Pressure-induced amorphization of YVO4:Eu3+ nanoboxes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1088/0957-4484/27/2/025701
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2013-46649-C4-4-P/ES/NANO-GRANATES DOPADOS CON IONES DE TIERRAS RARAS BAJO CONDICIONES EXTREMAS PARA APLICACIONES EN FOTONICA Y SENSORES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2013-46649-C4-3-P/ES/ESTUDIO AB INITIO DE OXIDO METALICOS, MATERIALES Y NANOMATERIALES BAJO CONDICIONES EXTREMAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MEC//CSD2007-00045/ES/MATERIA A ALTA PRESION/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2013-46649-C4-2-P/ES/OXIDOS METALICOS ABO3 EN CONDICIONES EXTREMAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Fundación CajaCanarias//ENER-01/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2013-46649-C4-1-P/ES/ORTOVANADATOS BAJO CONDICIONES EXTREMAS: SINTESIS Y CARACTERIZACION DE MATERIALES EN VOLUMEN Y NANOCRISTALES CON APLICACIONES TECNOLOGICAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DFG//RA2585%2F1-1/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Centro de Tecnologías Físicas: Acústica, Materiales y Astrofísica - Centre de Tecnologies Físiques: Acústica, Materials i Astrofísica es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Diseño para la Fabricación y Producción Automatizada - Institut de Disseny per a la Fabricació i Producció Automatitzada es_ES
dc.description.bibliographicCitation Ruiz Fuertes, J.; Gomis, O.; León Luis, SF.; Schrodt, N.; Manjón Herrera, FJ.; Ray, S.; Santamaría Pérez, D.... (2016). Pressure-induced amorphization of YVO4:Eu3+ nanoboxes. Nanotechnology. 27(2):025701-1-025701-8. https://doi.org/10.1088/0957-4484/27/2/025701 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1088/0957-4484/27/2/025701 es_ES
dc.description.upvformatpinicio 025701-1 es_ES
dc.description.upvformatpfin 025701-8 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 27 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 297736 es_ES
dc.identifier.eissn 1361-6528
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
dc.contributor.funder Fundación CajaCanarias es_ES
dc.contributor.funder Deutsche Forschungsgemeinschaft es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Alexander von Humboldt Foundation es_ES
dc.contributor.funder European Regional Development Fund es_ES
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