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Pd@UiO-66-Type MOFs Prepared by Chemical Vapor Infiltration as Shape-Selective Hydrogenation Catalysts

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Pd@UiO-66-Type MOFs Prepared by Chemical Vapor Infiltration as Shape-Selective Hydrogenation Catalysts

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dc.contributor.author Luz Mínguez, Ignacio es_ES
dc.contributor.author Roesler, Christoph es_ES
dc.contributor.author Epp, Konstantin es_ES
dc.contributor.author Llabrés i Xamena, Francesc Xavier es_ES
dc.contributor.author Fischer, Roland A. es_ES
dc.date.accessioned 2016-07-08T12:13:16Z
dc.date.available 2016-07-08T12:13:16Z
dc.date.issued 2015-08
dc.identifier.issn 1434-1948
dc.identifier.uri http://hdl.handle.net/10251/67383
dc.description.abstract [EN] Host-guest inclusion properties of UiO-66 and UiO-67 metal-organic frameworks have been studied using ferrocene (FeCp2) as probe molecule. According to variable-temperature solid-state H-1 and C-13 CP-MAS-NMR, two different environments exist for adsorbed FeCp2 inside UiO-66 and UiO-67, which have been assigned to octahedral and tetrahedral cavities. At room temperature, a rapid exchange between these two adsorption sites occurs in UiO-67, while at -80 degrees C the intracrystalline traffic of FeCp2 through the triangular windows is largely hindered. In UiO-66, FeCp2 diffusion is already impeded at room temperature, in agreement with the smaller pore windows. Palladium nanoparticles (Pd NPs) encapsulated inside UiO-66 and UiO-67 have been prepared by chemical vapor infiltration of (allyl)Pd(Cp) followed by UV light irradiation. Infiltration must be carried out at low temperature (-10 degrees C) to avoid uncontrolled decomposition of the organometallic precursor and formation of Pd NPs at the external surface of the MOF. The resulting Pd-MOFs are shape selective catalysts, as shown for the hydrogenation of carbonyl compounds with different steric hindrance. es_ES
dc.description.sponsorship Financial support from the Consolider-Ingenio 2010 (project MULTICAT), the Severo Ochoa program, and the Spanish Ministry of Science and Innovation (project MAT2011-29020-C02-01) is gratefully acknowledged. C. R. is grateful for a graduate student fellowship awarded by the Cluster of Excellence RESOLV (EXC 1069) funded by the German Deutsche Forschungsgemeinschaft (DFG). This project has further received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Skolodowska-Curie grant agreement, number 641887. en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof European Journal of Inorganic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Nanoparticles es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Hydrogenation es_ES
dc.subject Palladium es_ES
dc.subject Chemical vapor infiltration es_ES
dc.title Pd@UiO-66-Type MOFs Prepared by Chemical Vapor Infiltration as Shape-Selective Hydrogenation Catalysts es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/ejic.201500299
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-01/ES/CATALIZADORES HIBRIDOS MULTIFUNCIONALES BASADOS EN UNIDADES ESTRUCTURALES ORGANICAS-INORGANICAS UTILIZADOS EN REACCIONES CASCADA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/641887/EU/DEFect NETwork materials science and engineering/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DFG//EXC 1069/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Luz Mínguez, I.; Roesler, C.; Epp, K.; Llabrés I Xamena, FX.; Fischer, RA. (2015). Pd@UiO-66-Type MOFs Prepared by Chemical Vapor Infiltration as Shape-Selective Hydrogenation Catalysts. European Journal of Inorganic Chemistry. 23:3904-3912. https://doi.org/10.1002/ejic.201500299 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/ejic.201500299 es_ES
dc.description.upvformatpinicio 3904 es_ES
dc.description.upvformatpfin 3912 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 23 es_ES
dc.relation.senia 293454 es_ES
dc.contributor.funder European Commission
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Deutsche Forschungsgemeinschaft
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