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Binding and Fluorescent Sensing of Di-carboxylates by a Bis(calix[4]pyrrole)-Substituted BODIPY Dye

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Binding and Fluorescent Sensing of Di-carboxylates by a Bis(calix[4]pyrrole)-Substituted BODIPY Dye

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dc.contributor.author Gotor Candel, Raul Jesús es_ES
dc.contributor.author Costero Nieto, Ana María es_ES
dc.contributor.author Gaviña, P. es_ES
dc.contributor.author Gil Grau, Salvador es_ES
dc.contributor.author Parra Álvarez, Margarita es_ES
dc.date.accessioned 2016-07-11T08:41:50Z
dc.date.issued 2013-03
dc.identifier.issn 1434-193X
dc.identifier.uri http://hdl.handle.net/10251/67398
dc.description.abstract A bis(calix[4]pyrrole)-substituted BODIPY ditopic receptor 1 has been synthesised and characterised. The binding and sensing properties of 1 towards several aliphatic and aromatic dicarboxylates have been evaluated by using UV/Vis fluorescence and 1H NMR spectroscopy. The receptor strongly binds linear α,ω-dicarboxylates of appropriate lengths (C9 and C10) by acting as a cleft. For all dicarboxylates, the binding event is detected by a bathochromic shift in the UV/Vis spectra of the receptor and by strong quenching of its fluorescence. es_ES
dc.description.sponsorship Financial support from the Spanish Government (project MAT2009-14564-C04-02) and from Generalitat Valenciana (project PROMETEO/2009/095) is gratefully acknowledged. R. G. is grateful to the Spanish Ministry of Education for an FPU grant. SCSIE (Universidad de Valencia) is gratefully acknowledged for all of the equipment employed. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof European Journal of Organic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Sensors es_ES
dc.subject Fluorescent probes es_ES
dc.subject Dyes/pigments es_ES
dc.title Binding and Fluorescent Sensing of Di-carboxylates by a Bis(calix[4]pyrrole)-Substituted BODIPY Dye es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/ejoc.201201504
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2009-14564-C04-02/ES/Aproximacion Al Biomimetismo Usando Lenguas Electronicas Y Narices Para La Deteccion De Explosivos Y Agentes Nerviosos/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO09%2F2009%2F095/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.description.bibliographicCitation Gotor Candel, RJ.; Costero Nieto, AM.; Gaviña, P.; Gil Grau, S.; Parra Álvarez, M. (2013). Binding and Fluorescent Sensing of Di-carboxylates by a Bis(calix[4]pyrrole)-Substituted BODIPY Dye. European Journal of Organic Chemistry. 2013(8):1515-1520. https://doi.org/10.1002/ejoc.201201504 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/ejoc.201201504 es_ES
dc.description.upvformatpinicio 1515 es_ES
dc.description.upvformatpfin 1520 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 2013 es_ES
dc.description.issue 8 es_ES
dc.relation.senia 289148 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Generalitat Valenciana es_ES
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