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Mixed (Fe2+ and Cu2+) double metal hexacyanocobaltates as solid catalyst for the aerobic oxidation of oximes to carbonyl compounds

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Mixed (Fe2+ and Cu2+) double metal hexacyanocobaltates as solid catalyst for the aerobic oxidation of oximes to carbonyl compounds

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dc.contributor.author Garcia-Ortiz, Alma es_ES
dc.contributor.author Grirrane, Abdessamad es_ES
dc.contributor.author Reguera, Edilso es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2016-07-22T07:23:07Z
dc.date.available 2016-07-22T07:23:07Z
dc.date.issued 2014-03
dc.identifier.issn 0021-9517
dc.identifier.uri http://hdl.handle.net/10251/67995
dc.description.abstract Mixed Iron and copper hexacyanocolbatate is a suitable heterogeneous and recoverable catalyst for the aerobic oxidn. of oximes to the corresponding ketone. The reaction can be conveniently carried out in water-​ethanol 1:1 mixt. as solvent. The time-​conversion plots shows an induction period that do not correspond to the leaching of metal ions or to the damage of the crystal structure of the material. The proposed reaction mechanism is based on the cooperation of the Lewis acidity of iron with the ability of copper to interact with oxygen. Given the remarkable stability of metal hexacyanocobaltates and the large diversity of metals that can contain, the authors' reports opens the way for the general use of these affordable and accessible solids as heterogeneous catalysts. es_ES
dc.description.sponsorship Alma Garcia thanks Mexican CONACYT for financial support for her stay at Valencia. E.R. thanks the support provided by CONACyT through the Projects 129048 and 174247. en_EN
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation Spanish ministry of Economy and Competitiveness CTQ2012-32315 es_ES
dc.relation Generalidad Valenciana 2012-014 es_ES
dc.relation Mexican CONACYT at Valencia es_ES
dc.relation CONACyT 129048 174247 es_ES
dc.relation.ispartof Journal of Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Catalytic aerobic oxidation es_ES
dc.subject Exacyanocobaltates as solid catalysts es_ES
dc.subject Oxidation of oximes es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Mixed (Fe2+ and Cu2+) double metal hexacyanocobaltates as solid catalyst for the aerobic oxidation of oximes to carbonyl compounds es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.jcat.2013.12.011
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Garcia-Ortiz, A.; Grirrane, A.; Reguera, E.; García Gómez, H. (2014). Mixed (Fe2+ and Cu2+) double metal hexacyanocobaltates as solid catalyst for the aerobic oxidation of oximes to carbonyl compounds. Journal of Catalysis. 311:386-392. doi:10.1016/j.jcat.2013.12.011 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.jcat.2013.12.011 es_ES
dc.description.upvformatpinicio 386 es_ES
dc.description.upvformatpfin 392 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 311 es_ES
dc.relation.senia 285115 es_ES
dc.identifier.eissn 1090-2694


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