- -

Alkyltributylphosphonium chloride ionic liquids: synthesis, physicochemical properties and crystal structure

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Alkyltributylphosphonium chloride ionic liquids: synthesis, physicochemical properties and crystal structure

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Adamova, Gabriela...et ...
Tamaño: 1.543Mb
Formato: PDF
Descripción: Versión del Autor.
Abrir
[Cerrado]
Nombre: Gabriela Adamová; ...
Tamaño: 1.799Mb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author Adamova, Gabriela es_ES
dc.contributor.author Gardas, Ramesh L. es_ES
dc.contributor.author Nieuwenhuyzen, Mark es_ES
dc.contributor.author Vaca Puga, Alberto es_ES
dc.contributor.author Rebelo, Luis Paulo N. es_ES
dc.contributor.author Robertson, Allan J. es_ES
dc.contributor.author Seddon, Kenneth R. es_ES
dc.date.accessioned 2016-09-06T15:55:55Z
dc.date.available 2016-09-06T15:55:55Z
dc.date.issued 2012
dc.identifier.issn 1477-9226
dc.identifier.uri http://hdl.handle.net/10251/68915
dc.description.abstract [EN] A series of alkyltributylphosphonium chloride ionic liquids, prepared from tributylphosphine and the respective 1-chloroalkane, CnH2n+1Cl (where n = 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 12 or 14), is reported. This work is a continuation of an extended series of tetraalkylphosphonium ionic liquids, where the focus is on the variability of n and its impact on the physical properties, such as melting points/glass transitions, thermal stability, density and viscosity. Experimental density and viscosity data were interpreted using QPSR and group contribution methods and the crystal structure of propyl(tributyl) phosphonium chloride is detailed. es_ES
dc.description.sponsorship This work was funded by Cytec Canada, Inc. G.A. would like to thank Dr Douglas Harris (Cytec) for fruitful comments and advice at the beginning of this work; Prof. Chris Strauss, Dr Markus Fanselow and Dr Giulia Fiorani for microwave assistance and helpful guidance, and Prof. P.R. Raithby for the X-ray diffraction data collection. L.P.N.R. thanks Fundacao para a Ciencia e Tecnologia, Portugal, for support under grants PTDC/QUI-QUI/101794/2008 and PTDC/QUI/71331/2006.
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Dalton Transactions es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Quaternary phosphonium cations es_ES
dc.subject High-pressure densities es_ES
dc.subject Electrochemical properties es_ES
dc.subject Thermodynamic properties es_ES
dc.subject Organic-solvents es_ES
dc.subject Temperature es_ES
dc.subject Salts es_ES
dc.subject Ammonium es_ES
dc.subject Bromide es_ES
dc.subject Iodide es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Alkyltributylphosphonium chloride ionic liquids: synthesis, physicochemical properties and crystal structure es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c1dt10466g
dc.relation.projectID info:eu-repo/grantAgreement/FCT/3599-PPCDT/101794/PT/Molecular Modeling of Ionic Liquids: from Structure to Thermodynamics./
dc.relation.projectID info:eu-repo/grantAgreement/FCT/3599-PPCDT/71331/PT/Waste Elimination using Ionic Liquid Bio-Engineered Eukariotic Organisms/
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Adamova, G.; Gardas, RL.; Nieuwenhuyzen, M.; Vaca Puga, A.; Rebelo, LPN.; Robertson, AJ.; Seddon, KR. (2012). Alkyltributylphosphonium chloride ionic liquids: synthesis, physicochemical properties and crystal structure. Dalton Transactions. 41(27):8316-8332. doi:10.1039/c1dt10466g es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c1dt10466g es_ES
dc.description.upvformatpinicio 8316 es_ES
dc.description.upvformatpfin 8332 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 41 es_ES
dc.description.issue 27 es_ES
dc.relation.senia 232653 es_ES
dc.identifier.pmid 22679620
dc.contributor.funder Fundação para a Ciência e a Tecnologia, Portugal


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem