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High-speed living polymerization of polar vinyl monomers by self-healing silylium catalysts

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High-speed living polymerization of polar vinyl monomers by self-healing silylium catalysts

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Zhang, Y.; Lay, F.; García García, P.; List, B.; Chen, EY-. (2010). High-speed living polymerization of polar vinyl monomers by self-healing silylium catalysts. Chemistry - A European Journal. 16(34):10462-10473. doi:10.1002/chem.201000961

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/70140

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Title: High-speed living polymerization of polar vinyl monomers by self-healing silylium catalysts
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] This contribution describes the development and demonstration of the ambient-temperature, high-speed living polymerization of polar vinyl monomers (M) with a low silylium catalyst loading (<= 0.05 mol (X) relative to ...[+]
Subjects: Anions , Brønsted acids , Polar vinyl monomers , Polymerization , Silicon
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201000961
Publisher:
Wiley
Publisher version: http://dx.doi.org/ 10.1002/chem.201000961
Thanks:
The work carried out at CSU was supported by the National Science Foundation (NSF-0848845). We thank Boulder Scientific Co. for the research gifts of B(C6F5)3, [Ph3C]+[B(C6F5)4] , and [HN(Me2)Ph]+[B- (C6F5)4]
Type: Artículo

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