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Spin crossover in iron(II) complexes with ferrocene-bearing triazole-pyridine ligands

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Spin crossover in iron(II) complexes with ferrocene-bearing triazole-pyridine ligands

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dc.contributor.author Romero Morcillo, Tania es_ES
dc.contributor.author Valverde Muñoz, Francisco Javier es_ES
dc.contributor.author Piñeiro López, Lucía es_ES
dc.contributor.author Muñoz Roca, María del Carmen es_ES
dc.contributor.author Romero, Tomás es_ES
dc.contributor.author Molina, Pedro es_ES
dc.contributor.author Real, José A. es_ES
dc.date.accessioned 2016-09-27T16:26:41Z
dc.date.available 2016-09-27T16:26:41Z
dc.date.issued 2015
dc.identifier.issn 1477-9226
dc.identifier.uri http://hdl.handle.net/10251/70512
dc.description.abstract In the search for new multifunctional spin crossover molecular materials, here we describe the synthesis, crystal structures and magnetic and photomagnetic properties of the complexes trans-[Fe(Fctzpy)2(NCX)2]·CHCl3 where Fc-tzpy is the ferrocene-appended ligand 4-(2-pyridyl)-1H-1,2,3-triazol- 1-ylferrocene, X = S (1) and X = Se (2). Both complexes display thermal- and light-induced (LIESST) spin crossover properties characterised by T1/2 = 85 and 168 K, ΔS = 55 and 66 J K−1 mol−1 , ΔH = 4.7 and 11.1 kJ mol−1 and TLIESST = 47 K and 39 K for 1 and 2 respectively. The crystal structure of 1 and 2 measured at 275 K is consistent with the iron(II) ion in the high-spin state while the crystal structure of 2 at 120 K denotes the occurrence of complete transformation to the low-spin state. es_ES
dc.description.sponsorship The research reported here was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) and FEDER funds (CTQ2013-46275-P) and Generalitat Valenciana (PROMETEO/2012/049). T.R.M. and F.J.V.M. thank MINECO for a FPI grant. L.P.L. thanks the Generalitat Valenciana and the Universidad de Valencia for a predoctoral fellowship. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Dalton Transactions es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Spin crossover in iron(II) complexes with ferrocene-bearing triazole-pyridine ligands es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c5dt03084f
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2013-46275-P/ES/SENSORES Y MEMORIAS BASADOS EN MATERIALES BIESTABLES CON TRANSICION DE ESPIN/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F049/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Romero Morcillo, T.; Valverde Muñoz, FJ.; Piñeiro López, L.; Muñoz Roca, MDC.; Romero, T.; Molina, P.; Real, JA. (2015). Spin crossover in iron(II) complexes with ferrocene-bearing triazole-pyridine ligands. Dalton Transactions. 44:18911-18918. https://doi.org/10.1039/c5dt03084f es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c5dt03084f es_ES
dc.description.upvformatpinicio 18911 es_ES
dc.description.upvformatpfin 18918 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 44 es_ES
dc.relation.senia 295340 es_ES
dc.identifier.eissn 1477-9234
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Universitat de València es_ES
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