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New insights into the role of the electronic properties of oxide promoters in Rh-catalyzed selective synthesis of oxygenates from synthesis gas.

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New insights into the role of the electronic properties of oxide promoters in Rh-catalyzed selective synthesis of oxygenates from synthesis gas.

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Prieto González, G.; Concepción Heydorn, P.; Martinez Feliu, A.; Mendoza, E. (2011). New insights into the role of the electronic properties of oxide promoters in Rh-catalyzed selective synthesis of oxygenates from synthesis gas. Journal of Catalysis. 280(2):274-288. doi:10.1016/j.jcat.2011.03.025.

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Título: New insights into the role of the electronic properties of oxide promoters in Rh-catalyzed selective synthesis of oxygenates from synthesis gas.
Autor:
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Fecha difusión:
Resumen:
[EN] A series of 2.5% Rh/M@Al2O3 model catalysts were prepared by supporting Rh on high-area gamma-Al2O3, resulting in a surface covered by a monolayer (4.5-7 atoms/nm(2)) of MO promoter oxides (M = Fe, V. Nb, Ta, Ti, Y, ...[+]
Palabras clave: Synthesis gas , Oxygenates , Rhodium , Promoters , Electronic properties , Model catalysts , At-work CO-FTIR
Derechos de uso: Cerrado
Fuente:
Journal of Catalysis. (issn: 0021-9517 )
DOI: 10.1016/j.jcat.2011.03.025
Editorial:
Elsevier
Versión del editor: https://dx.doi.org/10.1016/j.jcat.2011.03.025
Tipo: Artículo

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