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Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles

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Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2016-10-04T10:30:09Z
dc.date.available 2016-10-04T10:30:09Z
dc.date.issued 2014-08-21
dc.identifier.issn 0306-0012
dc.identifier.uri http://hdl.handle.net/10251/71103
dc.description.abstract [EN] Metal-organic frameworks (MOFs) are finding increasing application as solid catalysts for liquid phase reactions leading to the synthesis of fine chemicals. In the present review we have focused on those reports describing the use of MOFs as catalysts for the synthesis of N-containing heterocycles that is a class of organic compounds with high added value due to their therapeutic use as drugs and their remarkable biological activities. After an introduction describing relevant structural features of MOFs and the nature of their active sites, this manuscript is organized according to the type of N-containing heterocycle synthesized employing MOFs as catalysts including pyrimidines, N-substituted piperidines, quinolines, indoles, N-substituted imidazoles, triazoles and heterocyclic amides. Special attention has been paid to the structural stability of MOFs under the reaction conditions, to the occurrence of metal leaching and reusability. The final section of this review provides some concluding remarks and future prospects for the field, with emphasis on showing the superiority of MOFs with respect to other solid catalysts for this type of liquid phase organic reactions and pointing out that the final goal in this research would be the use of these materials as catalysts in real industrial synthesis. es_ES
dc.description.sponsorship A.D.M. thanks University Grants Commission (UGC), New Delhi, for the award of Assistant Professorship under its Faculty Recharge Programme. Financial support by the Spanish Ministry of Economy and Competitiveness (CTQ-2012-32315 and Severo Ochoa) and Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. The research leading to these results has received partial funding from the European Community’s Seventh Framework Programme (FP7/2007–2013) under grant agreement no. 228862.
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation MINECOCTQ-2012-32315 es_ES
dc.relation GV/PROMETEO/2012-014 es_ES
dc.relation.ispartof Chemical Society Reviews es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject EFFICIENT HETEROGENEOUS CATALYST es_ES
dc.subject PALLADIUM NANOPARTICLES es_ES
dc.subject COORDINATION POLYMERS es_ES
dc.subject FRIEDLANDER REACTION es_ES
dc.subject COUPLING REACTION es_ES
dc.subject INHIBITORS es_ES
dc.subject ARYLATION es_ES
dc.subject COPPER es_ES
dc.subject MOFS es_ES
dc.subject PROPARGYLAMINES es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/C3CS60442J
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; García Gómez, H. (2014). Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles. Chemical Society Reviews. 43(16):5750-5765. https://doi.org/10.1039/C3CS60442J es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c3cs60442j es_ES
dc.description.upvformatpinicio 5750 es_ES
dc.description.upvformatpfin 5765 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 43 es_ES
dc.description.issue 16 es_ES
dc.relation.senia 286140 es_ES
dc.identifier.eissn 1460-4744
dc.contributor.funder European Commission
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder Generalitat Valenciana


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