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Deactivation of Cu-3(BTC)(2) in the Synthesis of 2-Phenylquinoxaline

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Deactivation of Cu-3(BTC)(2) in the Synthesis of 2-Phenylquinoxaline

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2016-10-05T09:54:51Z
dc.date.available 2016-10-05T09:54:51Z
dc.date.issued 2015-08
dc.identifier.issn 1011-372X
dc.identifier.uri http://hdl.handle.net/10251/71217
dc.description.abstract [EN] Cu-3(BTC)(2) deactivates by deterioration of its crystal structure during the use of this metal organic framework as catalyst in the synthesis of 2-phenylquinoxaline from phenacylbromide and o-phenylenediamine at room temperature. The material resulting from the use of Cu-3(BTC)(2) as catalyst was characterized by powder XRD, UV-Vis diffuse reflectance spectra and EPR showing that the crystal structure collapses and Cu2+ becomes reduced under the reaction conditions. es_ES
dc.description.sponsorship A.D.M. thanks University Grants Commission (UGC), New Delhi for the award of Assistant Professorship under its Faculty Recharge Programme. ADM also thanks Department of Science and Technology, India for the financial support through Fast Track project (SB/FT/CS-166/2013). Financial support by the Spanish Ministry of Economy and Competitiveness (CTQ-2012-32315 and Severo Ochoa) and Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. The research leading to these results has received partial funding from the European Community's Seventh Framework Programme (FP7/2007-2013) under Grant Agreement No. 228862. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag es_ES
dc.relation Department of Science and Technology, India/SB/FT/CS-166/2013 es_ES
dc.relation MINECO/CTQ-2012-32315 es_ES
dc.relation GV/PROMETEO/2012-014 es_ES
dc.relation.ispartof Catalysis Letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject 2-Phenylquinoxaline es_ES
dc.subject Cu-3(BTC)(2) es_ES
dc.subject 2 as catalyst es_ES
dc.subject Phenylquinoxaline es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Metal organic frameworks es_ES
dc.subject Heterocycle synthesis es_ES
dc.subject Catalyst stability es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Deactivation of Cu-3(BTC)(2) in the Synthesis of 2-Phenylquinoxaline es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10562-015-1497-4
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Alvaro Rodríguez, MM.; García Gómez, H. (2015). Deactivation of Cu-3(BTC)(2) in the Synthesis of 2-Phenylquinoxaline. Catalysis Letters. 145(8):1600-1605. doi:10.1007/s10562-015-1497-4 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10562-015-1497-4 es_ES
dc.description.upvformatpinicio 1600 es_ES
dc.description.upvformatpfin 1605 es_ES
dc.type.version info:eu repo/semantics/publishedVersion es_ES
dc.description.volume 145 es_ES
dc.description.issue 8 es_ES
dc.relation.senia 298323 es_ES
dc.identifier.eissn 1572-879X
dc.contributor.funder Department of Science and Technology, India
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder Generalitat Valenciana
dc.contributor.funder European Commission


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