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dc.contributor.author | Serrano Aroca, Ángel | es_ES |
dc.contributor.author | Monleón Pradas, Manuel | es_ES |
dc.contributor.author | Gómez Ribelles, José Luís | es_ES |
dc.contributor.author | Rault, J. | es_ES |
dc.date.accessioned | 2016-10-06T12:09:39Z | |
dc.date.available | 2016-10-06T12:09:39Z | |
dc.date.issued | 2015-11 | |
dc.identifier.issn | 0014-3057 | |
dc.identifier.uri | http://hdl.handle.net/10251/71308 | |
dc.description.abstract | Thermal analysis of water in reinforce hydrogels of plasma-polymerised poly(2-hydroxyethyl acrylate) (plPHEA) grafted onto macroporous poly(methyl methacrylate) (PMMA) are explained in a simple thermodynamic framework based on the transition diagram. Water in bulk PHEA was also analysed for comparison with plPHEA. These two hydrophilic polymers were prepared with a broad range of water mass fractions from 0.05 to 0.72. Thermal transition diagrams of water/PHEA and water/plPHEA were determined showing less undercooling of water crystallisation in plPHEA than in PHEA. Kinetics of water crystallisation for high and low water contents were studied in both hydrophilic systems following several thermal treatments. Water crystallises much faster in plPHEA than in PHEA for high water contents. For low water contents, crystallisation becomes possible holding at 30 degrees C for some time due to water segregation in both PHEA systems. However, much less water is segregated from the water/plPHEA mixture due to the influence of the hydrophobic component. | es_ES |
dc.description.sponsorship | This work was supported by a Marie Curie Host Fellowship and by the Spanish Science and Technology Ministry through the MAT2001-2678-C02-01 and MAT2002-04239-C03-03 projects. CIBER-BBN is an initiative funded by the VI National R&D&i Plan 2008-2011, Iniciativa Ingenio 2010, Consolider Program, CIBER Actions and financed by the Instituto de Salud Carlos III with assistance from the European Regional Development Fund. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | European Polymer Journal | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Hydrogels | es_ES |
dc.subject | plPHEA | es_ES |
dc.subject | Poly(methyl methacrylate) | es_ES |
dc.subject | Thermal analysis | es_ES |
dc.subject | Kinetics of crystallisation | es_ES |
dc.subject.classification | MAQUINAS Y MOTORES TERMICOS | es_ES |
dc.title | Thermal analysis of water in reinforced plasma-polymerised poly(2-hydroxyethyl acrylate) hydrogels | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.eurpolymj.2015.05.032 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICYT//MAT2002-04239-C03-03/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICYT//MAT2001-2678-C02-01/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada | es_ES |
dc.description.bibliographicCitation | Serrano Aroca, Á.; Monleón Pradas, M.; Gómez Ribelles, JL.; Rault, J. (2015). Thermal analysis of water in reinforced plasma-polymerised poly(2-hydroxyethyl acrylate) hydrogels. European Polymer Journal. 72:523-534. https://doi.org/10.1016/j.eurpolymj.2015.05.032 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.eurpolymj.2015.05.032 | es_ES |
dc.description.upvformatpinicio | 523 | es_ES |
dc.description.upvformatpfin | 534 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 72 | es_ES |
dc.relation.senia | 299919 | es_ES |
dc.identifier.eissn | 1873-1945 | |
dc.contributor.funder | Ministerio de Ciencia y Tecnología | es_ES |
dc.contributor.funder | Instituto de Salud Carlos III | es_ES |
dc.contributor.funder | Centro de Investigación Biomédica en Red en Bioingeniería, Biomateriales y Nanomedicina | es_ES |
dc.contributor.funder | European Commission |