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Spectroscopic, calorimetric, and catalytic evidences of hydrophobicity on Ti-MCM-41 silylated materials for olefin epoxidations

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Spectroscopic, calorimetric, and catalytic evidences of hydrophobicity on Ti-MCM-41 silylated materials for olefin epoxidations

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Silvestre Albero, J.; Domine ., ME.; Jorda Moret, JL.; Navarro Villalba, MT.; Rey Garcia, F.; Rodriguez-Reinoso, F.; Corma Canós, A. (2015). Spectroscopic, calorimetric, and catalytic evidences of hydrophobicity on Ti-MCM-41 silylated materials for olefin epoxidations. Applied Catalysis A: General. 507:14-25. doi:10.1016/j.apcata.2015.09.029

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Title: Spectroscopic, calorimetric, and catalytic evidences of hydrophobicity on Ti-MCM-41 silylated materials for olefin epoxidations
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
tHydrophobic Ti-MCM-41 samples prepared by post-synthesis silylation treatment demonstrate to behighly active and selective catalysts in olefins epoxidation by using organic hydroperoxides as oxidizingagents in liquid phase ...[+]
Subjects: Hydrophobic materials , Ti-MCM-41 catalyst , Silylation treatment , Immersion calorimetry , Catalytic epoxidation
Copyrigths: Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
Source:
Applied Catalysis A: General. (issn: 0926-860X ) (eissn: 1873-3875 )
DOI: 10.1016/j.apcata.2015.09.029
Publisher:
Elsevier
Publisher version: http://dx.doi.org/10.1016/j.apcata.2015.09.029
Thanks:
The authors gratefully acknowledge financial support of Spanish Government (MAT2012-38567-C02-01, Consolider-Ingenio 2010-Multicat CSD-2009-00050 and Severo Ochoa SEV-2012-0267) and Generalitat Valenciana (Project Prometeo). ...[+]
Type: Artículo

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