Mikami, Y.; Dhakshinamoorthy, A.; Alvaro Rodríguez, MM.; García Gómez, H. (2013). Catalytic activity of unsupported gold nanoparticles. Catalysis Science and Technology. 3(1):58-69. doi:10.1039/c2cy20068f
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/71584
Title:
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Catalytic activity of unsupported gold nanoparticles
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Author:
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Mikami, Yusuke
Dhakshinamoorthy, Amarajothi
Alvaro Rodríguez, Maria Mercedes
García Gómez, Hermenegildo
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UPV Unit:
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Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
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Issued date:
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Abstract:
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[EN] This article reviews some of the compelling evidence showing that colloidal gold nanoparticles without any solid support exhibit intrinsic catalytic activity for some of the typical gold-catalyzed reactions including ...[+]
[EN] This article reviews some of the compelling evidence showing that colloidal gold nanoparticles without any solid support exhibit intrinsic catalytic activity for some of the typical gold-catalyzed reactions including CO oxidation, aerobic oxidation of alcohols and diols, borohydride reductions and carbon-carbon cross coupling reaction among other reactions. A critical view of the state-of-the-art indicating open issues such as the role of the nature and concentration of the ligand and the possibility of preparing colloidal samples with preferential crystallographic planes is provided.
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Subjects:
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Aerobic alcohol oxidation
,
Temperature co oxidation
,
Liquid-phase oxidation
,
Selective oxidation
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Colloidal gold
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Particle size
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Chemoselective hydrogenation
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Crystal structure
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Room temperature
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Facile synthesis
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Copyrigths:
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Cerrado |
Source:
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Catalysis Science and Technology. (issn:
2044-4753
) (eissn:
2044-4761
)
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DOI:
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10.1039/c2cy20068f
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Publisher:
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Royal Society of Chemistry
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Publisher version:
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http://dx.doi.org/10.1039/c2cy20068f
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Project ID:
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MICINN/CTQ2009-15865
MICINN/CTQ2010-18671
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Thanks:
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Financial support by the Spanish Ministry of Science and Innovation (CTQ2009-15865, CTQ2010-18671 and Consolider Multicat) is gratefully acknowledged.
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Type:
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Artículo
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