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Iron(III) metal-organic frameworks as solid Lewis acids for the isomerization of alpha-pinene oxide

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Iron(III) metal-organic frameworks as solid Lewis acids for the isomerization of alpha-pinene oxide

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Nombre: Amarajothi;Alvaro;H. ...
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dc.contributor.author Amarajothi, Dhakshina Moorthy es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author Chevreau, Hubert es_ES
dc.contributor.author Horcajada Campos, Patricia es_ES
dc.contributor.author Devic, Thomas es_ES
dc.contributor.author Serre, Christian es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2016-10-11T06:55:11Z
dc.date.available 2016-10-11T06:55:11Z
dc.date.issued 2012
dc.identifier.issn 2044-4753
dc.identifier.uri http://hdl.handle.net/10251/71586
dc.description.abstract [EN] A series of Fe3+-containing porous metal-organic frameworks (MOFs), including the commercial iron trimesate Basolite F-300 or Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate) and the synthetic iron terephthalate MIL-88B (Fe3O(BDC)(3)X, X = Cl, OH, BDC = 1,4-benzenedicarboxylate), iron naphthalenedicarboxylate MIL-88C (Fe3O(NDC)(3)X, X = Cl, OH, NDC = 1,6-naphthalenedicarboxylate), iron trimesate MIL-100 (Fe3O(BTC)(2)X, X = Cl, OH) and iron azobenzenetetracarboxylate soc-MOF(Fe) or MIL-127 (Fe6O2(Tazb)(3)X-2, X = Cl, OH, Tazb = 3,3',5,5'-azobenzenetetracarboxylate; MIL stands for Materials from Institut Lavoisier), have been tested for the rearrangement of alpha-pinene oxide to camphonelal and isopinocamphone in the absence of solvent. Conversions of about 10% with 50% selectivity towards camphonelal were obtained. This catalytic performance has been compared with that of the copper trimesate Basolite C-300 or HKUST-1 of formula Cu-3(BTC)(2) and the aluminium terephthalate Basolite A-100 or MIL-53(Al) of formula Al(OH)(BDC) as well as with some homogeneous (ZnCl2, Cu(NO3)(2), Al(NO3)(3)) and heterogeneous (Fe3+-exchanged Y-zeolite) Lewis acids. Fe(BTC) also exhibits catalytic activity for the rearrangement of other epoxides (styrene, cyclohexene and norbornene oxides) under solventless conditions. Some partial deactivation of the Fe(BTC) with a slight degradation of the structure has nevertheless been observed. es_ES
dc.description.sponsorship Financial support by the Spanish DGI (CTQ2009-11587, CTQ2010-18671 and CONSOLIDER MULTICAT) is gratefully acknowledged. Funding of European Commission through an integrated FP7 project MACADEMIA (FP7/2007-2013 Nr. 228862) is also acknowledged. Authors thank G. Maurin for kindly simulating accessible surface areas of the open form of flexible MIL-88 solids. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science and Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject HETEROGENEOUS CATALYSIS es_ES
dc.subject EFFICIENT es_ES
dc.subject SORPTION es_ES
dc.subject MOFS es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Iron(III) metal-organic frameworks as solid Lewis acids for the isomerization of alpha-pinene oxide es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c2cy00376g
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2009-11587/
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2010-18671/ES/APLICACION DE SOLIDOS RETICULARES METAL-ORGANICO MODIFICADOS COMO CATALIZADORES HETEROGENEOS EN PROCESOS DE OXIDACION AEROBICA Y EN REACCIONES PROMOVIDAS POR ACIDOS DE LEWIS/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Amarajothi, DM.; Alvaro Rodríguez, MM.; Chevreau, H.; Horcajada Campos, P.; Devic, T.; Serre, C.; García Gómez, H. (2012). Iron(III) metal-organic frameworks as solid Lewis acids for the isomerization of alpha-pinene oxide. Catalysis Science and Technology. 2(2):324-330. https://doi.org/10.1039/c2cy00376g es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c2cy00376g es_ES
dc.description.upvformatpinicio 324 es_ES
dc.description.upvformatpfin 330 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 2 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 240406 es_ES
dc.contributor.funder European Commission
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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