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Silica supported copper and cerium oxide catalysts for ethyl acetate oxidation

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Silica supported copper and cerium oxide catalysts for ethyl acetate oxidation

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dc.contributor.author Tsoncheva, Tanya es_ES
dc.contributor.author Issa, Gloria es_ES
dc.contributor.author Blasco Lanzuela, Teresa es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Dimitrov, Momtchil es_ES
dc.contributor.author Hernández Morejudo, Selene es_ES
dc.contributor.author Kovacheva, Daniela es_ES
dc.contributor.author Atanasova, Genoveva es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2016-10-14T10:32:40Z
dc.date.available 2016-10-14T10:32:40Z
dc.date.issued 2013-08-15
dc.identifier.issn 0021-9797
dc.identifier.uri http://hdl.handle.net/10251/71821
dc.description.abstract [EN] The formation of active sites in the silica supported copper and cerium oxide hi-component catalysts for total oxidation of ethyl acetate was studied by Nitrogen physisorption, XRD, XPS, UV-Vis, Raman, FTIR of adsorbed CO spectroscopies and TPR. It was found that the interaction between the copper oxide nano-particles and the supported on the silica ceria ones is realized with the formation of interface layer of penetrated into ceria lattice copper ions in different oxidative state. This type of interaction improves the dispersion of copper oxide particles and provides higher accessibility of the reactants to the copper active sites even at low copper amount. (C) 2013 Elsevier Inc. All rights reserved. es_ES
dc.description.sponsorship The paper is published with the support of Project No. BG051PO001-3.3-05/0001. Financial support of BAS, FNI of Bulgarian Ministry of Education, Project (sic)HTC/(sic)01/8, DGICYT in Spain (Project CTQ2012-37925-C03-01) and bilateral project Bulgarian Spain Inter-academic Exchange Agreement (Project 2009BG0002) are also acknowledged.
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Colloid and Interface Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Silica supported catalyst es_ES
dc.subject Copper and cerium oxide es_ES
dc.subject Ethyl acetate oxidation es_ES
dc.subject Active sites es_ES
dc.title Silica supported copper and cerium oxide catalysts for ethyl acetate oxidation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.jcis.2013.05.005
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-37925-C03-01/ES/CATALIZADORES PARA LA ENERGIA Y EL MEDIOAMBIENTE: ACTIVACION SELECTIVA DE ENLACES S-H Y C-H/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MON//BG051PO001-3.3.05-0001/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Tsoncheva, T.; Issa, G.; Blasco Lanzuela, T.; Concepción Heydorn, P.; Dimitrov, M.; Hernández Morejudo, S.; Kovacheva, D.... (2013). Silica supported copper and cerium oxide catalysts for ethyl acetate oxidation. Journal of Colloid and Interface Science. 404:155-160. https://doi.org/10.1016/j.jcis.2013.05.005 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.jcis.2013.05.005 es_ES
dc.description.upvformatpinicio 155 es_ES
dc.description.upvformatpfin 160 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 404 es_ES
dc.relation.senia 258591 es_ES
dc.identifier.pmid 23743049
dc.contributor.funder Ministry of Education and Science, Bulgaria
dc.contributor.funder Ministerio de Economía y Competitividad


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