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Towards the design of organocatalysts for nerve agents remediation: The case of the active hydrolysis of DCNP (a Tabun mimic) catalyzed by simple amine-containing derivatives

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Towards the design of organocatalysts for nerve agents remediation: The case of the active hydrolysis of DCNP (a Tabun mimic) catalyzed by simple amine-containing derivatives

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Barba Bon, A.; Martínez-Máñez, R.; Sancenón Galarza, F.; Costero Nieto, AM.; Gil Grau, S.; Pérez, F.; Llopis, E. (2015). Towards the design of organocatalysts for nerve agents remediation: The case of the active hydrolysis of DCNP (a Tabun mimic) catalyzed by simple amine-containing derivatives. Journal of Hazardous Materials. 298:73-82. doi:10.1016/j.jhazmat.2015.04.083

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Título: Towards the design of organocatalysts for nerve agents remediation: The case of the active hydrolysis of DCNP (a Tabun mimic) catalyzed by simple amine-containing derivatives
Autor:
Entidad UPV: Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic
Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
We report herein a study of the hydrolysis of Tabun mimic DCNP in the presence of different amines, aminoalcohols and glycols as potential suitable organocatalysts for DCNP degradation. Experiments were performed in CD3CN ...[+]
Palabras clave: Diethylcyanophosphonate , Nerve agent simulant , Hydrolysis , Organocatalysts , Kinetics
Derechos de uso: Cerrado
Fuente:
Journal of Hazardous Materials. (issn: 0304-3894 ) (eissn: 1873-3336 )
DOI: 10.1016/j.jhazmat.2015.04.083
Editorial:
Elsevier
Versión del editor: http://dx.doi.org/10.1016/j.jhazmat.2015.04.083
Agradecimientos:
This research has been supported by the Ministerio de Educacion y Ciencia (MAT2012-38429-004). A.B.B. acknowledges being awarded a pre-doctoral FPI fellowship. SCSIE (Universidad de Valencia) is gratefully acknowledged for ...[+]
Tipo: Artículo

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