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Zeolite- and MgO-supported rhodium complexes and rhodium clusters: Tuning catalytic properties to control carbon carbon vs. carbon hydrogen bond formation reactions of ethene in the presence of H2

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Zeolite- and MgO-supported rhodium complexes and rhodium clusters: Tuning catalytic properties to control carbon carbon vs. carbon hydrogen bond formation reactions of ethene in the presence of H2

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Serna Merino, PM.; Gates, BC. (2013). Zeolite- and MgO-supported rhodium complexes and rhodium clusters: Tuning catalytic properties to control carbon carbon vs. carbon hydrogen bond formation reactions of ethene in the presence of H2. Journal of Catalysis. 308:201-212. doi:10.1016/j.jcat.2013.07.005

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Título: Zeolite- and MgO-supported rhodium complexes and rhodium clusters: Tuning catalytic properties to control carbon carbon vs. carbon hydrogen bond formation reactions of ethene in the presence of H2
Autor:
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Fecha difusión:
Resumen:
[EN] Essentially molecular rhodium catalysts were made from Rh(C2R4)(2)(acetylacetonate) on zeolite HY and on MgO and characterized by infrared and X-ray absorption spectroscopies. The supported rhodium species anchored ...[+]
Palabras clave: Catalysis by rhodium , Zeolite-supported catalysts , Carbon–carbon bond formation , Metal/acid cooperative mechanisms
Derechos de uso: Cerrado
Fuente:
Journal of Catalysis. (issn: 0021-9517 )
DOI: 10.1016/j.jcat.2013.07.005
Editorial:
Elsevier
Versión del editor: http://dx.doi.org/10.1016/j.jcat.2013.07.005
Código del Proyecto: info:eu-repo/grantAgreement/EC/FP7/253129/EU
Agradecimientos:
The research was supported by the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement PIOF-GA-2009-253129 (P.S.) and by DOE Basic Energy Sciences (FG02-04ER15513). We thank the DOE Division of ...[+]
Tipo: Artículo

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