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dc.contributor.author | Amr, Fares Ibrahim | es_ES |
dc.contributor.author | Vila, Carlos | es_ES |
dc.contributor.author | Blay, Gonzalo | es_ES |
dc.contributor.author | Muñoz Roca, María del Carmen | es_ES |
dc.contributor.author | Pedro, José R. | es_ES |
dc.date.accessioned | 2016-11-04T14:19:40Z | |
dc.date.available | 2016-11-04T14:19:40Z | |
dc.date.issued | 2016-05-19 | |
dc.identifier.issn | 1615-4150 | |
dc.identifier.uri | http://hdl.handle.net/10251/73326 | |
dc.description.abstract | A quinine-derived thiourea catalysed the enantioselective addition of 4-substituted pyrazolones to isatin-derived ketimines, providing a variety of aminooxindole-pyrazolone adducts containing congested vicinal tetrasubstituted stereocentres with excellent outcomes (up to 98% yield, >20:1 dr and 98% ee). | es_ES |
dc.description.sponsorship | Financial support from the MINECO (Gobierno de Espana and FEDER (EU)) (CTQ2013-47949-P) and from Generalitat Valenciana (ISIC2012/001) is gratefully acknowledged. C. V. thanks MINECO for JdC contract. Access to NMR, MS and X-ray facilities from the Servei central de support a la investigacio experimental (SCSIE)-UV is also acknowledged. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Wiley | es_ES |
dc.relation.ispartof | Advanced Synthesis and Catalysis | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Asymmetric catalysis | es_ES |
dc.subject | Isatin-derived ketimines | es_ES |
dc.subject | Organocatalysis | es_ES |
dc.subject | Pyrazolones | es_ES |
dc.subject | Quaternary stereocenters | es_ES |
dc.subject.classification | FISICA APLICADA | es_ES |
dc.title | Organocatalytic Enantioselective Alkylation of Pyrazol-3-ones with Isatin-Derived Ketimines: Stereocontrolled Construction of Vicinal Tetrasubstituted Stereocenters | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/adsc.201600036 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2013-47494-P/ES/NUEVOS RETOS EN EL DESARROLLO DE PROCESOS ENANTIOSELECTIVOS DE FORMACION DE ENLACES C-C MEDIANTE CATALISIS DUAL COOPERATIVA/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//ISIC%2F2012%2F001/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny | es_ES |
dc.description.bibliographicCitation | Amr, FI.; Vila, C.; Blay, G.; Muñoz Roca, MDC.; Pedro, JR. (2016). Organocatalytic Enantioselective Alkylation of Pyrazol-3-ones with Isatin-Derived Ketimines: Stereocontrolled Construction of Vicinal Tetrasubstituted Stereocenters. Advanced Synthesis and Catalysis. 358(10):1583-1588. https://doi.org/10.1002/adsc.201600036 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/adsc.201600036 | es_ES |
dc.description.upvformatpinicio | 1583 | es_ES |
dc.description.upvformatpfin | 1588 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 358 | es_ES |
dc.description.issue | 10 | es_ES |
dc.relation.senia | 316156 | es_ES |
dc.identifier.eissn | 1615-4169 | |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |