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Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworks

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Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworks

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dc.contributor.author Romero Morcillo, Tania es_ES
dc.contributor.author De la Pinta, Noelia es_ES
dc.contributor.author Callejo, Lorena M. es_ES
dc.contributor.author Piñeiro López, Lucía es_ES
dc.contributor.author Muñoz Roca, María del Carmen es_ES
dc.contributor.author Madariaga, Gotzon es_ES
dc.contributor.author Ferrer, Sacramento es_ES
dc.contributor.author Breczewski, Tomasz es_ES
dc.contributor.author Cortés, Roberto es_ES
dc.contributor.author Real, José A. es_ES
dc.date.accessioned 2016-11-04T14:38:06Z
dc.date.available 2016-11-04T14:38:06Z
dc.date.issued 2015-08-17
dc.identifier.issn 0947-6539
dc.identifier.uri http://hdl.handle.net/10251/73329
dc.description.abstract [Fe(tvp)(2)(NCS)(2)] (1) (tvp=trans-(4,4-vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two-dimensional grids. This uncommon supramolecular conformation defines square-sectional nanochannels (diagonal approximate to 2.2nm) in which inclusion molecules are located. The guest-loaded framework 1@guest displays complete thermal spin-crossover (SCO) behavior with the characteristic temperature T-1/2 dependent on the guest molecule, whereas the guest-free species 1 is paramagnetic whatever the temperature. For the benzene-guest derivatives, the characteristic SCO temperature T-1/2 decreases as the Hammet sigma(p) parameter increases. In general, the 1@guest series shows large entropy variations associated with the SCO and conformational changes of the interpenetrated grids that leads to a crystallographic-phase transition when the guest is benzonitrile or acetonitrile/H2O. es_ES
dc.description.sponsorship The research reported herein was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) and FEDER funds (CTQ2013-46275-P; MAT2012-34740), the Basque Government (project IT-779-13), and Generalitat Valenciana (PROMETEO/2012/049). T.R.M. thanks the Spanish Ministerio de Economia y Competitividad (MINECO) for a predoctoral grant (FPI.). L.P.-L. thanks the Generalitat Valenciana for a predoctoral fellowship in the frame of the project PROMETEO/2012/049. en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Inclusion compounds es_ES
dc.subject Interpenetration es_ES
dc.subject Iron es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Spin crossover es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworks es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201500310
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2012-34740/ES/SINTESIS, ESTRUCTURA Y PROPIEDADES DE NUEVOS MATERIALES FERROICOS Y MULTIFERROICOS./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2013-46275-P/ES/SENSORES Y MEMORIAS BASADOS EN MATERIALES BIESTABLES CON TRANSICION DE ESPIN/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Eusko Jaurlaritza//IT-779-13/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F049/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny es_ES
dc.description.bibliographicCitation Romero Morcillo, T.; De La Pinta, N.; Callejo, LM.; Piñeiro López, L.; Muñoz Roca, MDC.; Madariaga, G.; Ferrer, S.... (2015). Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworks. Chemistry - A European Journal. 21(34):12112-12120. https://doi.org/10.1002/chem.201500310 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/chem.201500310 es_ES
dc.description.upvformatpinicio 12112 es_ES
dc.description.upvformatpfin 12120 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 21 es_ES
dc.description.issue 34 es_ES
dc.relation.senia 293076 es_ES
dc.identifier.eissn 1521-3765
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Eusko Jaurlaritza es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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