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Isolation Structural Assignment and Synthesis of N-(2-Methyl-3-oxodecanoyl)-2-pyrroline a New Natural Product from Penicillium brevicompactum with in vivo Anti-Juvenile Hormone Activity

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Isolation Structural Assignment and Synthesis of N-(2-Methyl-3-oxodecanoyl)-2-pyrroline a New Natural Product from Penicillium brevicompactum with in vivo Anti-Juvenile Hormone Activity

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Moya, P.; Cantin Sanz, A.; Castillo López, MÁ.; Primo Millo, J.; Miranda Alonso, MÁ.; Primo Yufera, E. (1998). Isolation Structural Assignment and Synthesis of N-(2-Methyl-3-oxodecanoyl)-2-pyrroline a New Natural Product from Penicillium brevicompactum with in vivo Anti-Juvenile Hormone Activity. Journal of Organic Chemistry. 63(23):8530-8535. doi:10.1021/jo972267v

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/74801

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Title: Isolation Structural Assignment and Synthesis of N-(2-Methyl-3-oxodecanoyl)-2-pyrroline a New Natural Product from Penicillium brevicompactum with in vivo Anti-Juvenile Hormone Activity
Author:
UPV Unit: Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Agrónomos - Escola Tècnica Superior d'Enginyers Agrònoms
Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería Agronómica y del Medio Natural - Escola Tècnica Superior d'Enginyeria Agronòmica i del Medi Natural
Issued date:
Abstract:
[EN] A new natural product with in vivo anti-juvenile hormone (JK) activity, N-(2-methyl-3-oxodecanoyl)-2-pyrroline (2), has been isolated from Penicillium brevicompactum Dierckx. Its structure has been tentatively assigned ...[+]
Subjects: Reverse-turn peptidomimetics , Beta-keto-esters , Electroorganic chemistry , Electrochemical cyclization , Conformational analysis , Organic-synthesis , Biosynthesis , Dipeptides , Discovery , Inhibitor
Copyrigths: Reserva de todos los derechos
Source:
Journal of Organic Chemistry. (issn: 0022-3263 )
DOI: 10.1021/jo972267v
Publisher:
American Chemical Society
Publisher version: https://dx.doi.org/10.1021/jo972267v
Description: Supporting Information Available: 1H-NMR and 13CNMR spectra of compounds 2-6 (12 pages).
Thanks:
The authors acknowledge the financial support of the Institucio´ Valenciana d’Estudis i Investigacio´ (fellowship to A.C.), Comisión Interministerial de Ciencia y Tecnología (CICYT), and Consejeria de Agricultura P. y A. ...[+]
Type: Artículo

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