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Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex

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Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex

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Piñeiro López, L.; Ortega Villar, N.; Muñoz Roca, MDC.; Molnar, G.; Cirera, J.; Moreno Esparza, R.; Ugalde Saldivar, VM.... (2016). Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex. Chemistry - A European Journal. 22(36):12741-12751. doi:10.1002/chem.201601172

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/75106

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Title: Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex
Author:
UPV Unit: Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny
Issued date:
Abstract:
The highly stable nitrosyl iron(II) mononuclear complex [Fe(bztpen)(NO)](PF6)(2) (bztpen=N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethylenediamine) displays an S=1/2 <-> S=3/2 spin crossover (SCO) behavior (T-1/2=370 K, Delta ...[+]
Subjects: Antiferromagnetic coupling , Molecular structures , Nitrosyl complexes , Spin crossover
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 ) (eissn: 1521-3765 )
DOI: 10.1002/chem.201601172
Publisher:
Wiley
Publisher version: http://dx.doi.org/10.1002/chem.201601172
Thanks:
The research reported here was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) and FEDER funds (CTQ2013-46275-P, CTQ2015-64579-C3-1-P, and Unidad de Excelencia Maria de Maeztu MDM-2015-0538) and ...[+]
Type: Artículo

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