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Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex

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Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex

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Piñeiro López, L.; Ortega Villar, N.; Muñoz Roca, MDC.; Molnar, G.; Cirera, J.; Moreno Esparza, R.; Ugalde Saldivar, VM.... (2016). Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex. Chemistry - A European Journal. 22(36):12741-12751. https://doi.org/10.1002/chem.201601172

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/75106

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Title: Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex
Author: Piñeiro López, Lucía Ortega Villar, Norma Muñoz Roca, María del Carmen Molnar, Gabor Cirera, Jordi Moreno Esparza, Rafael Ugalde Saldivar, Victor M. Bousseksou, Azzedine Ruiz, Eliseo Real, Jose A.
UPV Unit: Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny
Issued date:
Abstract:
The highly stable nitrosyl iron(II) mononuclear complex [Fe(bztpen)(NO)](PF6)(2) (bztpen=N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethylenediamine) displays an S=1/2 <-> S=3/2 spin crossover (SCO) behavior (T-1/2=370 K, Delta ...[+]
Subjects: Antiferromagnetic coupling , Molecular structures , Nitrosyl complexes , Spin crossover
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 ) (eissn: 1521-3765 )
DOI: 10.1002/chem.201601172
Publisher:
Wiley
Publisher version: http://dx.doi.org/10.1002/chem.201601172
Project ID:
info:eu-repo/grantAgreement/MINECO//CTQ2013-46275-P/ES/SENSORES Y MEMORIAS BASADOS EN MATERIALES BIESTABLES CON TRANSICION DE ESPIN/
info:eu-repo/grantAgreement/MINECO//CTQ2015-64579-C3-1-P/ES/ESTRUCTURA ELECTRONICA Y PROPIEDADES DE MOLECULAS Y SOLIDOS/
info:eu-repo/grantAgreement/MINECO//MDM-2015-0538/ES/INSTITUTO DE CIENCIA MOLECULAR/
info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F049/
Thanks:
The research reported here was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) and FEDER funds (CTQ2013-46275-P, CTQ2015-64579-C3-1-P, and Unidad de Excelencia Maria de Maeztu MDM-2015-0538) and ...[+]
Type: Artículo

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