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dc.contributor.author | Escolástico Rozalén, Sonia | es_ES |
dc.contributor.author | Serra Alfaro, José Manuel | es_ES |
dc.date.accessioned | 2017-01-10T11:05:39Z | |
dc.date.available | 2017-01-10T11:05:39Z | |
dc.date.issued | 2015-09-01 | |
dc.identifier.issn | 0376-7388 | |
dc.identifier.uri | http://hdl.handle.net/10251/76546 | |
dc.description.abstract | This work presents the structural and electrochemical characterization of mixed conducting materials based on the system Nd5.5W1-xUxO11.25-delta where x = 0.1, 0.5 and 1. The evolution of the crystalline structure is studied as a function of the sintering temperature and the U content in the oxide lattice. The influence of hydration and pO(2) as well as the H/D isotopic effect are studied by DC-electrochemical measurements under reducing environments. Hydrogen permeation is carried out for Nd5.5WO11.25-delta and Nd5.5W0.9U0.O-1(11.25-delta) compounds in the range from 650 to 750 degrees C. Finally, stability of the developed materials at 800 degrees C is evaluated in contact with CO2-rich gas streams. This work completes previous reported studies On Ln(6-x)WO(12-y) based materials that show the possibility of engineering the conductivity properties of the Ln(6-x)WO(12-y) just by doping strategies. (C) 2015 Published by Elsevier B.V | es_ES |
dc.description.sponsorship | Financial support by the Spanish Government (Grants ENE2011-24761, CSD-2009-0050 and SEV-2012-0267) and the Helmholtz Association of German Research Centers through the portfolio topic MEM-BRAIN is kindly acknowledged. The authors are indebted to M. Fabuel for sample preparation. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Journal of Membrane Science | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Proton conductor | es_ES |
dc.subject | Hydrogen membrane | es_ES |
dc.subject | Tungstate | es_ES |
dc.subject | Uranium | es_ES |
dc.subject | Hydrogen permeation | es_ES |
dc.title | Nd5.5W1xUxO11.25-delta system: Electrochemical characterization and hydrogen permeationstudy | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.memsci.2015.04.017 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//ENE2011-24761/ES/DESARROLLO DE NUEVOS DISPOSITIVOS IONICOS PARA LA PRODUCCION EFICIENTE Y SOSTENIBLE DE ENERGIA Y PRODUCTOS QUIMICOS%2FCOMBUSTIBLES/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Escolástico Rozalén, S.; Serra Alfaro, JM. (2015). Nd5.5W1xUxO11.25-delta system: Electrochemical characterization and hydrogen permeationstudy. Journal of Membrane Science. 489:112-118. https://doi.org/10.1016/j.memsci.2015.04.017 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.memsci.2015.04.017 | es_ES |
dc.description.upvformatpinicio | 112 | es_ES |
dc.description.upvformatpfin | 118 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 489 | es_ES |
dc.relation.senia | 290151 | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | Helmholtz Association of German Research Centers | es_ES |