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Nd5.5W1xUxO11.25-delta system: Electrochemical characterization and hydrogen permeationstudy

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Nd5.5W1xUxO11.25-delta system: Electrochemical characterization and hydrogen permeationstudy

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dc.contributor.author Escolástico Rozalén, Sonia es_ES
dc.contributor.author Serra Alfaro, José Manuel es_ES
dc.date.accessioned 2017-01-10T11:05:39Z
dc.date.available 2017-01-10T11:05:39Z
dc.date.issued 2015-09-01
dc.identifier.issn 0376-7388
dc.identifier.uri http://hdl.handle.net/10251/76546
dc.description.abstract This work presents the structural and electrochemical characterization of mixed conducting materials based on the system Nd5.5W1-xUxO11.25-delta where x = 0.1, 0.5 and 1. The evolution of the crystalline structure is studied as a function of the sintering temperature and the U content in the oxide lattice. The influence of hydration and pO(2) as well as the H/D isotopic effect are studied by DC-electrochemical measurements under reducing environments. Hydrogen permeation is carried out for Nd5.5WO11.25-delta and Nd5.5W0.9U0.O-1(11.25-delta) compounds in the range from 650 to 750 degrees C. Finally, stability of the developed materials at 800 degrees C is evaluated in contact with CO2-rich gas streams. This work completes previous reported studies On Ln(6-x)WO(12-y) based materials that show the possibility of engineering the conductivity properties of the Ln(6-x)WO(12-y) just by doping strategies. (C) 2015 Published by Elsevier B.V es_ES
dc.description.sponsorship Financial support by the Spanish Government (Grants ENE2011-24761, CSD-2009-0050 and SEV-2012-0267) and the Helmholtz Association of German Research Centers through the portfolio topic MEM-BRAIN is kindly acknowledged. The authors are indebted to M. Fabuel for sample preparation. en_EN
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Membrane Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Proton conductor es_ES
dc.subject Hydrogen membrane es_ES
dc.subject Tungstate es_ES
dc.subject Uranium es_ES
dc.subject Hydrogen permeation es_ES
dc.title Nd5.5W1xUxO11.25-delta system: Electrochemical characterization and hydrogen permeationstudy es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.memsci.2015.04.017
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//ENE2011-24761/ES/DESARROLLO DE NUEVOS DISPOSITIVOS IONICOS PARA LA PRODUCCION EFICIENTE Y SOSTENIBLE DE ENERGIA Y PRODUCTOS QUIMICOS%2FCOMBUSTIBLES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Escolástico Rozalén, S.; Serra Alfaro, JM. (2015). Nd5.5W1xUxO11.25-delta system: Electrochemical characterization and hydrogen permeationstudy. Journal of Membrane Science. 489:112-118. https://doi.org/10.1016/j.memsci.2015.04.017 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.memsci.2015.04.017 es_ES
dc.description.upvformatpinicio 112 es_ES
dc.description.upvformatpfin 118 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 489 es_ES
dc.relation.senia 290151 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Helmholtz Association of German Research Centers es_ES


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