Abidi, M.; López-Bernabeu, S.; Huerta, F.; Montilla-Jiménez, F.; Besbes-Hentati, S.; Morallón, E. (2016). The chemical and electrochemical oxidative polymerization of 2-amino-4-tert-butylphenol. Electrochimica Acta. 212:958-965. https://doi.org/10.1016/j.electacta.2016.07.060
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/77530
Title:
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The chemical and electrochemical oxidative polymerization of 2-amino-4-tert-butylphenol
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Author:
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Abidi, Maali
López-Bernabeu, Sara
Huerta, Francisco
Montilla-Jiménez, Francisco
Besbes-Hentati, Salma
Morallón, Emilia
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UPV Unit:
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Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera
Universitat Politècnica de València. Escuela Politécnica Superior de Alcoy - Escola Politècnica Superior d'Alcoi
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Issued date:
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Abstract:
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[EN] Poly(2-amino-4-tert-butylphenol), poly(2A-4TBP), was synthesized from monomer aqueous solution using either electrochemical or chemical oxidation procedures. Several spectroscopic characterization techniques were ...[+]
[EN] Poly(2-amino-4-tert-butylphenol), poly(2A-4TBP), was synthesized from monomer aqueous solution using either electrochemical or chemical oxidation procedures. Several spectroscopic characterization techniques were employed to gain information on the chemical structure and redox behavior of the obtained materials. It was found that the chemical polymerization product could be described as an oligomer mixture containing up to 16 monomer units. In parallel to other polymers derived from o-aminophenol, phenoxazine rings constitute also the basic structure of poly(2A-4TBP). In addition, the occurrence of N-N couplings, which are favored by the presence of the voluminous tert-butyl substituent, seems also relevant. No significant structural differences were found between the chemically or electrochemically synthesized materials. © 2016 Published by Elsevier Ltd.
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Subjects:
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Electrochemical polymerization
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In situ FTIR
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Polyaminophenol
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Copyrigths:
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Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
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Source:
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Electrochimica Acta. (issn:
0013-4686
)
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DOI:
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10.1016/j.electacta.2016.07.060
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Publisher:
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Elsevier
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Publisher version:
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http://dx.doi.org/10.1016/j.electacta.2016.07.060
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Conference name:
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4th International Symposium on Surface Imaging/Spectroscopy at the Solid/Liquid Interface (ISSIS)
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Conference place:
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Cracovia, Poland
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Conference date:
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September 02-04, 2015
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Project ID:
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info:eu-repo/grantAgreement/MINECO//MAT2013-42007-P/ES/FUNCIONALIZACION ELECTROQUIMICA DE MATERIALES AVANZADOS PARA APLICACIONES EN ENERGIA Y BIOSENSORES ELECTROQUIMICOS/
info:eu-repo/grantAgreement/GVA//PROMETEO%2F2013%2F038/ES/Desarrollo de nuevos electrodos y procesos químicos sostenibles para la detección de analitos obtenidos por microextracción líquido-líquido/
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Thanks:
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Financial support from the Spanish Ministerio de Economía y Competitividad and FEDER funds (MAT2013-42007-P) and from
the Generalitat Valenciana (PROMETEO2013/038) is gratefully acknowledged. M. Abidi thanks the Ministry ...[+]
Financial support from the Spanish Ministerio de Economía y Competitividad and FEDER funds (MAT2013-42007-P) and from
the Generalitat Valenciana (PROMETEO2013/038) is gratefully acknowledged. M. Abidi thanks the Ministry of Higher Education and Scientific Research of Tunisia for funding her stay at the University of Alicante.
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Type:
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Artículo
Comunicación en congreso
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