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Highly enantioselective copper(I)-catalyzed conjugate addition of 1,3-diynes to a,b-unsaturated trifluoromethyl ketones

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Highly enantioselective copper(I)-catalyzed conjugate addition of 1,3-diynes to a,b-unsaturated trifluoromethyl ketones

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Sanz-Marco, A.; Blay, G.; Muñoz Roca, MDC.; Pedro, J. (2015). Highly enantioselective copper(I)-catalyzed conjugate addition of 1,3-diynes to a,b-unsaturated trifluoromethyl ketones. Chemical Communications. (51):8958-8961. https://doi.org/10.1039/C5CC01676B

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Title: Highly enantioselective copper(I)-catalyzed conjugate addition of 1,3-diynes to a,b-unsaturated trifluoromethyl ketones
Author: Sanz-Marco, Amparo Blay, Gonzalo Muñoz Roca, María Del Carmen Pedro, J.R.
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
[EN] The conjugate diynylation of a,b-unsaturated trifluoromethyl ketones is carried out in the presence of a low catalytic load (2.5 mol%) of a copper(I)–MeOBIPHEP complex, triethylamine and a terminal 1,3-diyne. Pre ...[+]
Copyrigths: Reconocimiento (by)
Source:
Chemical Communications. (issn: 1359-7345 )
DOI: 10.1039/C5CC01676B
Publisher:
Royal Society of Chemistry
Publisher version: http://dx.doi.org/10.1039/C5CC01676B
Project ID:
info:eu-repo/grantAgreement/MINECO//CTQ2013-47494-P/ES/NUEVOS RETOS EN EL DESARROLLO DE PROCESOS ENANTIOSELECTIVOS DE FORMACION DE ENLACES C-C MEDIANTE CATALISIS DUAL COOPERATIVA./
GV/ISIC2012/ 001
Thanks:
Financial support from the Ministerio de Economia y Competitividad (MINECO-Gobierno de Espana) and FEDER (EU) (CTQ2013-47494-P) and from Generalitat Valenciana (ISIC2012/001) is gratefully acknowledged. A.S.-M. thanks the ...[+]
Type: Artículo

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