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dc.contributor.author | Tamaño-Machiavello, María Noel | es_ES |
dc.contributor.author | Bracke, Benjamin | es_ES |
dc.contributor.author | Costa, C.M. | es_ES |
dc.contributor.author | Lanceros-Mendez, Senentxu | es_ES |
dc.contributor.author | Sabater i Serra, Roser | es_ES |
dc.contributor.author | Gómez Ribelles, José Luís | es_ES |
dc.date.accessioned | 2017-04-27T11:19:57Z | |
dc.date.available | 2017-04-27T11:19:57Z | |
dc.date.issued | 2016-03-15 | |
dc.identifier.issn | 0887-6266 | |
dc.identifier.uri | http://hdl.handle.net/10251/80121 | |
dc.description.abstract | Polymer blend membranes have been obtained consisting of a hydrophilic and a hydrophobic polymers distributed in co-continuous phases. In order to obtain stable membranes in aqueous environments, the hydrophilic phase is formed by a poly(hydrohyethyl acrylate), PHEA, network while the hydrophobic phase is formed by poly(vinylidene fluorideco- trifluoroethylene) P(VDF-TrFE). To obtain the composites, in a first stage, P(VDF-TrFE) is blended with poly(ethylene oxyde) (PEO), the latter used as sacrificial porogen. P(VDF-TrFE)/PEO blend membranes were prepared by solvent casting at 708C followed by cooling to room temperature. Then PEO is removed from the membrane by immersion in water obtaining a P(VDF-TrFE) porous membrane. After removing of the PEO polymer, a P(VDF-TrFE) membrane results in which pores are collapsed. Nevertheless the pores reopen when a mixture of hydroxethyl acrylate (HEA) monomer, ethyleneglycol dimethacrylate (as crosslinker) and ethanol (as diluent) is absorbed in the membrane and subsequent polymerization yields hybrid hydrophilic/hydrophobic membranes with controlled porosity. The membranes are thus suitable for lithium-ion battery separator membranes and/or biostable supports for cell culture in biomedical applications. | es_ES |
dc.description.sponsorship | This work was funded by the Spanish Ministry of Economy and Competitiveness (MINECO) through the project MAT2013-46467-C4-1-R (including the FEDER financial support). The work of the Portuguese group was funded by FEDER funds through the "Programa Operacional Factores de Competitividade e COMPETE" and by national funds from Fundacao para a Ciencia e a Tecnologia, in the framework of the strategic project Strategic Project PEST-C/FIS/UI607/2014. We thank funding from "Matepro-Optimizing Materials and Processes, ref. NORTE-07-0124-FEDER-000037", co-funded by the "Programa Operacional Regional do Norte" (ON.2 e O Novo Norte), under the "Quadro de Referencia Estrategico Nacional" (QREN), through the "Fundo Europeu de Desenvolvimento Regional" (FEDER), and grant SFRH/BD/68499/2010 (C.M.C.). CIBER-BBN is an initiative funded by the VI National R&D&I Plan 2008-2011, Iniciativa Ingenio 2010, Consolider Program, CIBER Actions and financed by the Instituto de Salud Carlos III with assistance from the European Regional Development Fund. M.N.T.M. acknowledges the Programa de Ayuda de Investigacion y Desarrollo (PAID) of the Universitat Politecnica de Valencia for her doctoral grant. The authors acknowledge the assistance and advice of Electron Microscopy Service of the UPV. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Wiley | es_ES |
dc.relation.ispartof | Journal of Polymer Science Part B: Polymer Physics | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Hydrophilic | es_ES |
dc.subject | Hydrophobic | es_ES |
dc.subject | P(VDF-TrFE) | es_ES |
dc.subject | PHEA hydrogel | es_ES |
dc.subject | Porous membrane | es_ES |
dc.subject | Electron Microscopy Service of the UPV | |
dc.subject.classification | INGENIERIA ELECTRICA | es_ES |
dc.subject.classification | MAQUINAS Y MOTORES TERMICOS | es_ES |
dc.title | Hydrophobic/Hydrophilic P(VDF-TrFE)/PHEA Polymer Blend Membranes | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/polb.23959 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2013-46467-C4-1-R/ES/ESTIMULACION MECANICA LOCAL DE CELULAS MESENQUIMALES DE CARA A SU DIFERENCIACION OSTEOGENICA Y CONDROGENICA EN MEDICINA REGENERATIVA/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F68499%2F2010/PT/ELECTROACTIVE POLYMER BASED POROUS MEMBRANES FOR ENERGY STORAGE APPLICATIONS/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT//NORTE-07-0124-FEDER-000037/PT/Matepro – Optimizing Materials and Processes/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/FCT//PEST-C%2FFIS%2FUI607%2F2014/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny | es_ES |
dc.description.bibliographicCitation | Tamaño-Machiavello, MN.; Bracke, B.; Costa, C.; Lanceros-Mendez, S.; Sabater I Serra, R.; Gómez Ribelles, JL. (2016). Hydrophobic/Hydrophilic P(VDF-TrFE)/PHEA Polymer Blend Membranes. Journal of Polymer Science Part B: Polymer Physics. 54:672-679. https://doi.org/10.1002/polb.23959 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/polb.23959 | es_ES |
dc.description.upvformatpinicio | 672 | es_ES |
dc.description.upvformatpfin | 679 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 54 | es_ES |
dc.relation.senia | 301270 | es_ES |
dc.identifier.eissn | 1099-0488 | |
dc.contributor.funder | Ministerio de Economía, Industria y Competitividad | |
dc.contributor.funder | Fundação para a Ciência e a Tecnologia, Portugal |