- -

Processing and characterization of high environmental efficiency composites based on PLA and hazelnut shell flour (HSF) with biobased plasticizers derived from epoxidized linseed oil (ELO)

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

Processing and characterization of high environmental efficiency composites based on PLA and hazelnut shell flour (HSF) with biobased plasticizers derived from epoxidized linseed oil (ELO)

Show simple item record

Files in this item

dc.contributor.author Balart Gimeno, Javier Francisco es_ES
dc.contributor.author Fombuena Borrás, Vicent es_ES
dc.contributor.author Fenollar Gimeno, Octavio Ángel es_ES
dc.contributor.author Boronat Vitoria, Teodomiro es_ES
dc.contributor.author Sánchez Nacher, Lourdes es_ES
dc.date.accessioned 2017-05-17T07:20:36Z
dc.date.available 2017-05-17T07:20:36Z
dc.date.issued 2016-02-01
dc.identifier.issn 1359-8368
dc.identifier.uri http://hdl.handle.net/10251/81250
dc.description.abstract [EN] Different amounts of epoxidized linseed oil (ELO) have been added to poly(lactic acid)-PLA composites with hazelnut shell flour (HSF) to provide a plasticizing effect and improve the low intrinsic ductile properties of PLA/HSF composites. Mechanical, thermal, thermo-mechanical and dynamic mechanical properties have been studied in terms of the weight percentage ELO. Mechanical resistant properties in both tensile and flexural tests decrease with wt.% ELO while a remarkable increase with wt.% ELO is obtained. These results reveal a clear plasticization effect of ELO but, in addition, internal structure of PLA/HSF/ELO composites shows good PLA-HSF (matrix-particle) interactions so that indicating that ELO also provides a coupling effect between PLA matrix and HSF filler. ELO addition leads to a decrease in storage modulus (G ) obtained by dynamic mechanical thermal analysis (DMTA) in torsion mode thus giving clear evidence of the plasticization effect of ELO. Overall, the use of ELO in PLA/HSF composites is an attracting way to improve the low intrinsic fragility of these green composites; furthermore, ELO provides an improvement on thermal stability and a coupling effect between the polymer matrix and the surrounding lignocellulosic filler. es_ES
dc.description.sponsorship This research was supported by the Ministry of Economy and Competitiveness - MINECO, Grant Number: MAT2014-59242-C2-1-R. Authors also thank to "Conselleria d'Educacio, Cultura i Esport" - Generalitat Valenciana, Grant Number: GV/2014/008 for financial support.
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation MINECO/MAT2014-59242-C2-1-R es_ES
dc.relation GV/GV/2014/008 es_ES
dc.relation.ispartof Composites Part B: Engineering es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Particle-reinforcement es_ES
dc.subject Interface/interphase es_ES
dc.subject Mechanical testing es_ES
dc.subject Injection moulding es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Processing and characterization of high environmental efficiency composites based on PLA and hazelnut shell flour (HSF) with biobased plasticizers derived from epoxidized linseed oil (ELO) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.compositesb.2015.09.063
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Politécnica Superior de Alcoy - Escola Politècnica Superior d'Alcoi es_ES
dc.description.bibliographicCitation Balart Gimeno, JF.; Fombuena Borrás, V.; Fenollar Gimeno, OÁ.; Boronat Vitoria, T.; Sánchez Nacher, L. (2016). Processing and characterization of high environmental efficiency composites based on PLA and hazelnut shell flour (HSF) with biobased plasticizers derived from epoxidized linseed oil (ELO). Composites Part B: Engineering. 86:168-177. doi:10.1016/j.compositesb.2015.09.063 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.compositesb.2015.09.063
dc.description.upvformatpinicio 168 es_ES
dc.description.upvformatpfin 177 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 86 es_ES
dc.relation.senia 299081 es_ES
dc.identifier.eissn 1879-1069
dc.contributor.funder Ministerio de Economía y Competitividad (MINECO)
dc.contributor.funder Generalitat Valenciana (GV)


This item appears in the following Collection(s)

Show simple item record